Study questions benefits of spending on carbon capture – Chemistry World

An analysis of emissions data from two carbon capture facilities suggests that the technologies reduce carbon dioxide emissions less than previously assumed by climate models, and overall are less effective than replacing fossil fuels with renewable energy.1

Carbon capture and storage (CCS) has assumed a large role in potential strategies to limit global warming and mitigate the effects of climate change. Such technology removes carbon dioxide from power plant flue gas, or directly from the air, using a variety of separation methods including physical adsorption and separation using synthetic membranes. The captured carbon dioxide can then be stored in a variety of ways. It can be sequestered; pumped deep underground into geological formations where it is unlikely to re-enter the atmosphere, stored in a material or sold for industrial use.

Previous models predicted that even with an energy penalty for running capture equipment, removing up to 8090% of carbon dioxide emissions in a plant operating CCS was possible, relative to one without. However, Mark Jacobson at Stanford University in the US is sceptical. By analysing emissions data from both a coal power plant with retrofitted carbon capture and use (CCU) equipment, and a synthetic direct air carbon capture and use (SDACCU) plant, Jacobson found that previously assumed efficiencies of carbon dioxide capture have been overstated. Part of it is that data was not available. Before that data was available and before these plants had been built, people were just speaking theoretically.

Jacobson set out to provide a holistic view of the process. This involved accounting for upstream emissions associated with mining and transporting fossil fuels to a power plant, and the energy used by gas turbines to power the capture equipment. The study also considered the social cost of the technology, which Jacobson defines as the sum of the energy, health and climate costs incurred by its use factors that he says other studies have overlooked.

For the coal-CCU plant, Jacobson found net carbon dioxide removal values to be strikingly different to earlier predictions. I looked over a 20-year and 100-year timeframe of all the carbon dioxide emitted, which includes the upstream and combustion emissions, only 1011% was captured over a 20-year timeframe. Over a 100-year timeframe its between 2030%. Net carbon dioxide removal values do increase in alternative scenarios: using renewables to power the capture equipment, and replacing fossil-based energy generation entirely with renewable sources.

Jacobson says the latter is the best strategy not just for reducing carbon dioxide emissions, but also for minimising social costs. The most unhealthy components of air pollution, such as pollutants that form ozone those are increased because you have a new source of pollution from the natural gas [powering the CCU equipment] none of that is captured, he says. When you add it all together you have a huge increase in social cost, because the equipment is so expensive and the health costs are so high, and the climate cost is only slightly reduced.

Similarly for the SDACCU plant, which removes carbon dioxide directly from the air using gas-powered capture, Jacobson concludes that whilst some carbon dioxide is removed, the near doubling of the social cost per MWh of electricity makes it less efficient than replacing coal electricity with renewables. This, he argues, is down to the increased equipment cost and air pollution from mining drawbacks that renewables would eliminate. Using wind to replace coal was about one tenth the social cost of using natural gas to run the direct air capture (DAC) equipment. So its an enormous difference theres no reason in the world that anybody should try to pull carbon out of the air as opposed to using the same money to spend on renewable energy.

In contrast, Wim Turkenburg, an emeritus professor of science, technology and society at Utrecht University who has worked as part of the Intergovernmental Panel on Climate Change, is positive about the prospects for using carbon capture. When evaluating the performance of CCS and DAC technologies, the study refers to the present status of the technology, he comments. However, the performance of CCS and DAC can improve tremendously as a function of time, caused by technological learning.

Paul Fennell, a clean energy researcher at Imperial College London, UK, echoes Turkenburgs thoughts. The work appears to be based on the first few months that the CCS plant was open, and it is unlikely that this will be representative of a fully operational plant that has been operating past its start-up period.

Specifically, Turkenburg cites research from 2017 attempting to develop cleaner and highly efficient fossil fuel plants as an example of where CCS technology could be implemented in the future.2 That study explores how to develop a fossil fuel power plant with no (direct) carbon dioxide emissions, a high conversion efficiency and low projected capital, operation and maintenance costs.

However, Jacobson argues that this is still not an optimal solution when compared to a complete uptake of renewables. All such proposals require additional energy and cost, which must come from somewhere.

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Study questions benefits of spending on carbon capture - Chemistry World

Indians notebook: Terry Francona believes in the chemistry of current team – Akron Beacon Journal

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Indians notebook: Terry Francona believes in the chemistry of current team - Akron Beacon Journal

How We Found New Chemical Plants Are Being Built in South Louisianas Most Polluted Areas – ProPublica

ProPublica is a nonprofit newsroom that investigates abuses of power. Sign up for ProPublicas Big Story newsletter to receive stories like this one in your inbox as soon as they are published.

The data for our story and corresponding graphic comes from several sources. We provide details on each below.

The bulk of the analysis relies on data from the Risk-Screening Environmental Indicators (RSEI) model, which was developed by the U.S. Environmental Protection Agency. Manufacturing facilities with 10 or more employees in particular industries, which are in possession of chemical quantities above specific thresholds, are required to disclose information on their toxic emissions to the Toxics Release Inventory, a program administered by the EPA. The EPA releases this information online each year as required by the 1986 Emergency Planning and Community Right-to-Know Act. RSEI translates the TRI data, which is reported by weight, into values that reflect the relative risk to human health. These indicators allow regulators, companies and communities to assess risks and take action relative to a specific facility or waste stream.

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Our analysis uses RSEI data from 2017, the most recent year available. To understand the estimated impacts of industrial activity in neighborhoods near facilities, we looked at data at the most granular unit available 810-by-810-meter grid cells. By isolating chemical concentrations from individual facilities, we were able to identify the entities that pose the greatest potential health risks to communities along the lower Mississippi River.

In our interactive map, we visualized the estimated concentrations of cancer-causing chemicals generated from large industrial facilities. In order to compare those concentrations, we weighted them by a measure called the inhalation unit risk (IUR). A chemicals IUR is an estimate of the increased cancer risk an individual incurs if, over the course of their lifetime, they are continually exposed to the chemical at a concentration of 1 microgram per cubic meter of air. IUR values are published in the EPAs Integrated Risk Information System (IRIS). We refer to IUR-adjusted values throughout our article and graphic as toxic levels of cancer-causing chemicals. These values do not reflect non-cancer related toxicity.

Our tool lets readers see how cancer-weighted concentrations in their area compare with everywhere else in the following seven parishes on the lower Mississippi River: St. John, St. James, Ascension, Iberville, St. Charles, East Baton Rouge and West Baton Rouge. Our map uses a range of cancer risk similar to that of the EPAs National Air Toxics Assessment (NATA), which we describe in more detail in a later section. On the lower end of our scale is a cancer risk of 1 in 100,000. That is, if 100,000 people are exposed to the same concentration of a pollutant continuously over a presumed lifespan of 70 years, one person would likely contract cancer from the exposure. The high end of our scale is 1 in 1,000. In the cases where we show cancer-weighted toxicity for individual chemicals and facilities, we scale the map between 1 in 1 million and 1 in 1,000. Although we scale our map by cancer risk, the values we show do not convey absolute risk to individuals residing in these areas. We are illustrating toxic levels of cancer-causing chemicals, as modeled by RSEI. On the advice of experts in this field, our tool does not publish risks at the grid cell level. The EPA says RSEI does not perform a risk assessment, but is rather a screening-level tool to help identify situations of potential concern.

The text version of our story also uses RSEI data to analyze Louisianas improvements in toxic emissions over time, compared with the rest of the country. For that analysis, we used historical RSEI data, aggregated at the level of census block groups (data for 810-by-810-meter blocks is unavailable for years prior to 2015 in the most recent version of RSEI). The historical analysis included all chemicals, not just carcinogenic ones. We analyzed facility-level aggregated RSEI data from 1988 to 2017, every year that it was available.

In addition to determining the locations of greatest concern, ProPublica hired RSEI expert Michael Petroni to estimate increases in toxic levels of cancer-causing chemicals from new industrial plants and plant expansions that have either received approval or are currently pending approval from the Louisiana Department of Environmental Quality (DEQ). He modeled data for new industrial projects using the RSEI methodology. The data sources for that analysis are detailed in the following two sections.

For our investigation, we needed to determine where chemical companies are planning to build new and expanded plants along the lower Mississippi River. We filed several public records requests with the DEQ to obtain permit files of industrial projects that are pending approval or have already been approved by the agency.

We asked for all approved and pending air permits dating back to Jan. 1, 2015, in the seven parishes listed above.

Once we received the permit files, we excluded any projects that are not expansions or new facilities (many of the files we received were modifications of existing permits). Additionally, we only included projects that the EPA deems to be major sources of toxic air pollution. Such projects are required by federal law to receive Title V air permits before they can begin operating. A column in the data specifies each projects permit type. We filtered for initial Title V air permits, excluding other types of projects.

Once we had a list of approved and pending major-source industrial projects between Baton Rouge and New Orleans, we had to determine each projects proposed emissions. Inputs to the RSEI model include chemical name, pounds of the chemical released and other information specific to the source of the release, such as stack height and exit velocity. Stack height refers to the height at which pollutants are released to the air, through pipes, vents or other enclosed air streams. Exit velocity measures the speed at which pollutants escape into the air.

For industrial projects that have already received approval to begin operating, we pulled information on their allowable chemical releases from the Emissions Reporting and Inventory Center (ERIC), an online database administered by the DEQ. We also looked at proposed emissions information from Formosas two pending facilities in the DEQs Electronic Document Management System (EDMS) because its St. James complex is one of the largest and most expensive industrial projects in the states history, and the company was recently sued for polluting waterways in neighboring Texas. Formosa has said that the conditions of the settlement it reached with the state demonstrate its commitment to manufacturing its products in a safe and environmentally friendly manner.

The National Air Toxics Assessment (NATA) is a screening tool administered by the EPA to help state and local agencies identify pollutants, emission sources and locations of potential risks to public health. Unlike RSEI, which publishes relative toxicity information, NATA assigns estimated cancer risk scores to census tracts across the country. While our analysis did not use NATA data, we checked our results against it to ensure our results matched the locations NATA flagged for high cancer risk.

Spatial data in our interactive map came from several sources. Louisiana keeps a shapefile of parish boundaries on its website. The shapefile with 810-by-810-meter grid cells is downloadable from the U.S. EPAs RSEI site. The shapes of land parcels in St. James Parish owned by industrial companies were provided by Justin Kray, a data analyst with the Louisiana Bucket Brigade. Kray pulled information on existing industry in St. James from the Parish Assessors Office and 2017 aerial photography from the U.S. Department of Agriculture. Data on recent sales and transfers came from the St.
James Parish Clerk of Court.

Our graphic includes information on demographics in St. James Parish. These estimates were taken from the U.S. Census Bureaus 2013-2017 American Community Survey 5-Year Estimates.

Michael Petroni is a Ph.D. candidate and fellow of the Center for Environmental Medicine and Informatics at the State University of New York College of Environmental Science and Forestry.

Do you live in one of these affected parishes? Share your story with us. ProPublica and The Times-Picayune and The Advocate are investigating the massive chemical plants in the industrial stretch between New Orleans and Baton Rouge, and hearing from you will help us tell more stories.

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How We Found New Chemical Plants Are Being Built in South Louisianas Most Polluted Areas - ProPublica

New England Patriots: Building chemistry is an OTA storyline to watch – Musket Fire

Oct 30, 2016; New Orleans, LA, USA; New Orleans Saints wide receiver Brandin Cooks (10) runs past Seattle Seahawks defensive end Cassius Marsh (91) during the fourth quarter of a game at the Mercedes-Benz Superdome. The Saints defeated the Seahawks 25-20. Mandatory Credit: Derick E. Hingle-USA TODAY Sports

New England Patriots: Team earns B- re-grade from SI for 2014 NFL Draft by Matty Simo

New England Patriots 2016 Player Grade: Dion Lewis by Nick Ziegler

After winning the Super Bowl just a few months ago, the New England Patriots will be back on the field soon to attempt to repeat as champions.

This offseason has been a fairly good one for New England. Despite having a lot of key free agents on the defensive side of the ball, the Patriots used trades and free agency to help them create a solid roster.

Even though the Patriots had one of the best offenses in the NFL last season, the unit could be even better in 2017. One of the shocking moves for the Patriots this offseason was the trade that acquired Brandin Cooks.

After shipping their first round pick in a package to acquire Cooks, the Patriots will be getting a dynamic wide receiver. Cooks has been extremely good for the New Orleans Saints the past three seasons. On one of the best offenses in the league, Cooks had excellent chemistry with another great quarterback in Drew Brees.

With voluntary OTAs starting on Monday, seeing how Cooks and Brady develop chemistry will be one of the early storylines to watch according to Mike Reiss of ESPN.com.

The Patriots are loaded at wide receiver with the addition of speedy Brandin Cooks, who joins an already solid depth chart of Julian Edelman, Chris Hogan, Malcolm Mitchell and Danny Amendola. When watching an OTA, it is commonplace to hear quarterback Tom Brady talking to his pass-catchers about how precise he likes routes to be run as the work begins to develop a foundation to take into training camp. Cooks, in particular, will be one to watch.

The OTAs wont be open to the media until Thursday. However, the team will be able to get in some good work this week in their drills. With no pads, it will certainly be fun to watch players like Cooks go up against Malcolm Butler and Stephon Gilmore in practice.

As one of the most talented wide receivers Brady has ever played with, building chemistry with Cooks will be important. However, he should be able to make it a priority in the offseason to get used to throwing to his new weapon.

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New England Patriots: Building chemistry is an OTA storyline to watch - Musket Fire

Genetic engineering through click chemistry – The Biological SCENE

Gene therapy and a range of biological research rely on the efficient delivery of nucleic acids into cells through the process known as transfection. Most widely-used transfection approaches for mammalian cells rely on electrostatic forces, usually taking advantage of cationic reagents to bind to negatively-charged nucleic acids and form strong ionic complexes. Cells then grab these complexes and internalize them through a process called endocytosis. However, the concentration of positive charge in the reagents can kill cells, and some cellssuch as embryonic cells, neurons, or cells directly isolated from tissuedont incorporate the nucleic acids successfully.

Now researchers report a novel transfection technique, SnapFect, that relies on bio-orthogonal moleculesa class of chemically-reactive molecules that dont interfere with biological systems (ACS Cent. Sci. 2017, DOI: 10.1021/acscentsci.7b00132). The team designed nanoparticle liposomes carrying a bio-orthogonal ligand. When they add those fatty particles to cell culture, they fuse into the cell membrane within seconds, leaving the ketone ligand exposed on the surface. The team then packages the nucleic acids to be delivered in complementary lipid complexes decorated with oxyamines. When the oxyamine particles are added to the cells, these functional groups react quickly with the cell surface ketones. The membrane-bound nucleic-acid complex is then pulled into the cell via endocytosis, and the nucleic acid can be expressed. Its not based on electrostatics but on click chemistry, says Muhammad N. Yousaf, a chemical biologist at York University. Thats why basically every cell is transfected with the nucleic acid.

Commercial transfection reagents already bring in about $1.5 billion per year. Yousafs team compared SnapFect to two widely-used kits: Lipofectamine (Life Technologies) and ViaFect (Promega). SnapFect transfected cells with a 68% overall efficiency while the other two transfected 19% and 29%, respectively.

Yousaf launched a company called OrganoLinX that this month began selling SnapFect ($350 for 20-25 transfections). We focused on making [the kit] just as easy to use as other commercial products out there, he says.

Besides improving efficiency, researchers could also pre-treat one batch of cells to decorate them with ketones and then mix them with other cell types before adding nucleic acids. Just the pre-treated ones will be transfected, Yousaf explains. Its like precision transfection. Because the team can create a variety of complexes using the oxyamine particles, the technique can also deliver other molecules such as proteins into cells.

I think its an interesting step forward, says James H. Eberwine, a molecular neurobiologist at the University of Pennsylvaniaparticularly the techniques universal applicability to DNA, RNA, and proteins, as well as the specificity conferred by the click chemistry approach.

Eberwine adds that while the study compares SnapFect to two widely-used techniques, researchers often optimize those techniques for their particular applications and achieve much higher efficiencies than those noted in this study. I would certainly try it, he says, and if it really does have the higher efficiency then I could see value in doing this.

Currently cell surface modification with ketones must occur shortly before addition of the oxyamine-bundled cargo. But SnapFect would be especially powerful if the ketone modification was more permanent, Eberwine says. That way, researchers could pre-engineer the surface of immature cells, then allow those cells to develop, migrate, and find their place in the local microenvironment of an experimental system before they get transfected. This would be a real boon, he says.

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Genetic engineering through click chemistry - The Biological SCENE

Chemistry camp bonds over food science – Herald & Review

DECATUR Honeybees are smarter than people may realize.

They can do a dance to tell the others where they've found pollen. When the hive gets too populated, the queen takes a group and leaves to start a new colony, and the ones left behind know when their queen is gone and get busy choosing an egg to create into a new queen.

They also know when a person is afraid of them.

Chase Brown of Brown and Brown Farms in Warrensburg was the guest speaker at Millikin University's chemistry camp for high school students on Tuesday. The camp is a collaboration with the University of Illinois Extension and Richland Community College. It offers high school students hands-on research, lunches with food industry entrepreneurs like Brown, preparation for scholarship-ready science projects and a demonstration dinner to wind up the camp experience.

Brown has been a beekeeper, in addition to his other farm endeavors, for a few years.

MacArthur High School student Brian Spicer performs an experiment during the Millikin University High School Chemistry Camp at the Leighty-Tabor Science Center Tuesday.

I have an Amish friend who's had bees for years, Brown told the students. He said when he goes to the hive after a long day, when he's tired and stressed, he always gets stung. If he goes on a Saturday morning, with a cup of coffee, when he's relaxed, they never sting him.

Brown likes catching wild swarms of bees for his hives because they're already in search of a new hive and already acclimated to Illinois winters, he said. A swarm of bees on a table or tree is most likely a group with their queen looking for new quarters. Before they left the old hive, they gorged on honey, so they'll be mellow and unlikely to sting.

Do you want to get in a fight right after Thanksgiving dinner? Brown asked the students, who laughed at the idea.

Honeybees are endangered, and while scientists are studying the problem, the reasons are still not clear what is killing them off. Brown said he urges people not to spray or kill a swarm, but to call someone like him to come to get them.

We want to know what's killing them so we can stop doing it, he said.

Farming is not what it once was, he told the students, not even for a family farm like his. His grandfather farmed that land before him, and he farms it with his father now, but farming has become big business.

A tractors costs $600,000, and the plow attachment costs $80,000, he said. A bag of seed corn, which will plant 2 acres, is $200. The amount of money the Browns have to borrow to get the crop in is astronomical, he said, and if the weather or markets don't cooperate, it can create a real financial bind.

Times have been good in recent years, with a profit remaining after harvest, but one effect of that is a surplus crop, which means that there's less demand, and prices fall.

The Brown farm is diversified, with cattle and rabbits raised for market, alfalfa to feed their own animals and to sell, corn and soybeans as other Illinois farms have, wheat, hogs, the bees and chickens. Their animals are not given antibiotics unless they're sick and not sold to market until the antibiotics have left their systems, and their food is non-GMO, even though GMOs would make things simpler for them, because consumers prefer it.

Farmers do a little bit of everything, Brown said: He's an agronomist, a botanist, a chemist, though his degree from Illinois State University is in animal nutrition.

Meeting Brown was a lesson in practical application of chemistry and science in general, and students at the camp are also learning some food science, said Garrett Trimble, 17, who is home-schooled. One of the things they are working on is taffy.

We're seeing the effect of the different type of butter on the finished product, Trimble said. With unsalted butter, it takes much less time to cook it because the boiling point is different. He plans to major in chemistry in college but hasn't yet decided what career path to pursue.

Hannah Flickinger, 16, who is also home-schooled, has not yet taken a chemistry course, but it's an interest of hers and she thought the camp would be a good chance to work in a lab and get a head start.

It's a new thing I wanted to try because I'm taking dual-credit classes at Richland (Community College), so I'm taking chemistry next year, and I thought it would be a fun start for that, she said. Anesthesiology is what I'm interested in for a job right now, and there's a lot of chemistry in that.

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Chemistry camp bonds over food science - Herald & Review

Late in the Season, Grizzlies Still Seeking Consistency, Chemistry – Memphis Daily News

VOL. 132 | NO. 50 | Friday, March 10, 2017

Players and coach David Fizdale have had some, well, interesting things to say in the wake of that dreadful 122-109 loss to the NBA-worst Brooklyn Nets. But this isnt about one game, one lineup change or even one quote from Fizdale that at times has been taken out of context.

Grizzlies coach David Fizdale was more than a little frustrated with a recent loss to the lowly Brooklyn Nets. This is our lowest point, he said.

(AP Photo/Brandon Dill)

Yes, Fizdale said during a recent media scrum that he couldnt settle for mediocre play (good), he would continue to experiment with lineups (understandable) until I find something that works best and gives us the best chance at holding the trophy. And if people dont like it, they can kiss my (butt).

Understand, though, that Fizdale was not spitting fire when he said that. He was his usual measured self. If its possible to sound like a statesman while inviting all who disagree to kiss your backside, Fizdale did it. Theres a lesson in that for somebody with an overactive Twitter account, but we digress.

The truth is, the Grizzlies have been playing hide-and-seek with their consistency and their chemistry since Jan. 1. A couple of hours before the Nets game, Fizdale spoke of the teams .500 malaise. A couple of hours later, the Grizzlies were exactly 14-14 since Jan. 1 and when asked about the mood of the team the coach admitted, This is our lowest point.

But naturally it was Fizdales kiss my (butt) comment two days later that has gotten all the run. Fizdale had juggled the lineup for the Nets game, pulling out forward JaMychal Green and guard Tony Allen in favor of Brandan Wright and, ahem, rookie Andrew Harrison. The Harrison move garnered five points, one assist and two turnovers in 22 D-League-quality minutes.

No one could take issue with Fizdale wanting to shake things up a bit, but all of Memphis from inside the Grizzlies locker room to the man on the street reacted to his choice of moves with a collective SMH (Shaking My Head). It wasnt just who came into the starting lineup, it was that Chandler Parsons didnt come out of it. And that Zach Randolph, who has excelled playing off the bench (credit to Fizz on that one) only saw the floor for 16 minutes.

We dont have that much time to get ready for the playoffs, center and team captain Marc Gasol said. Its now that there has to be one goal, and thats whats best for the team not whats best for one guy or another guy.

Hmm, can read a bit into that cant you?

To be fair, Gasol wasnt necessarily speaking of Parsons or only about Parsons. There are plenty of concerns. Its just that the teams insistence on starting Parsons when his knees clearly arent healthy enough for him to approach the offensive production that netted him his four-year $94 million contract becomes a bigger albatross all the time.

Gasol often speaks of the teams need to be connected on defense (more on that in a moment), but they have not been particularly connected on offense. Common is the possession where Parsons has space on the wing and Gasol, who is a good passer, chooses to take the ball elsewhere. Rudy Gay was often accused of being a ball-stopper here (and he often was), but Parsons presence was supposed to make the ball move more, to give everyone more space to operate because his 3-point shooting was something to be feared.

Count on this: Right now, no opponent is scared they are going to be hurt by Chandler Parsons.

Perhaps the FedExForum visit from the hated Los Angeles Clippers, who were to be here on Thursday, March 9, will have proved to be some sort of elixir. But for more than two months, the Grizzlies have not sustained good play.

The Nets game wasnt just a blip and an embarrassment, though it was that, too. It was the model of how teams will continue to come at the Grizzlies.

Its drive Memphis, run them and drive them, Fizdale said. We couldnt guard them off the dribble. Thats really our biggest Achilles heel right now: handling speed off the dribble, getting back on defense, being quicker to the ball.

All of that was Fizdale at his diplomatic best, but basically saying what Dave Joerger said all too plainly: Compared to the rest of the NBA, the Grizzlies can look old and slow.

That said, effort is also part of the equation.

On the ball (defense), we gotta take more pride one-on-one, point guard Mike Conley said. Were relying on too many guys to help.

The Grizzlies are in the midst of a four-game homestand that continues with the Atlanta Hawks on Saturday, March 11, and the Milwaukee Bucks on Monday, March 13. After that, six of their next seven games are on the road and this includes consecutive games at San Antonio and Golden State. And that lone home game? Also against the Spurs.

There is no good time to be struggling, but this late with playoff seeding on the line is especially bad timing.

Were hitting adversity, said Fizdale. We dont get to choose when that happens.

They do get to choose how they react to it.

We have a lot of guys here that have been through a lot, Gasol said. And I trust every single one of them that theyre going to do the right thing.

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Late in the Season, Grizzlies Still Seeking Consistency, Chemistry - Memphis Daily News

Power of science: Warriors thrive with chemistry experiment – Daily Commercial

By Janie McCauley / The Associated Press

OAKLAND, Calif. Zaza Pachulia holds his own during competitive games of poker on the airplane alongside Stephen Curry and Klay Thompson they call it the "Good Guys Table." Andre Iguodala and JaVale McGee, one-time teammates with Denver reunited in Oakland, hold secret chats.

"We're building an empire," Iguodala joked. "We've got secret stuff we can't talk about."

Jonnie West son of Hall of Famer and Warriors executive Jerry West joins Curry, Pachulia and Thompson for their card games.

"It depends how Klay feels. If he's tired, then no card game," Pachulia said.

With all that was made before the season about adding Kevin Durant to an already star-studded roster, Golden State's players have jelled just fine. The Warriors are gearing up for what they hope is another championship run, and chemistry sure isn't holding them back.

Two-time reigning MVP Curry and KD love to watch each other accomplish amazing things on the floor, along with Draymond Green and Thompson and all of the others who contribute off the bench.

Curry initially allowed Durant to find his groove, then began to assert himself more and increase his shots. Experience playing together is the biggest factor to keep building team bonds, if you ask Iguodala.

"Weathering storms builds chemistry and adversity builds chemistry," he said. "The season's long and you want to have all types of ups and downs. And that's where you build it the most, and off the court, plane rides. I think when you play with teammates seven, eight years, you're still building throughout that time. You continue to learn about each other. You've just got to understand that that's part of the process and you've got to want to learn from one another."

The Warriors are counting on every advantage they can gain, on and off the court. During flights, team dinners, anywhere.

After a heartbreaking Game 7 to end last season's NBA Finals, Golden State's players want nothing short of a championship. Many of them got a taste winning the title two years ago for the franchise's first in 40 years.

Steve Kerr, the reigning NBA Coach of the Year, gets a kick out of watching his teams come together each year.

"It's one of my favorite parts of coaching honestly, is seeing how a team comes together, seeing the relationships develop, seeing guys laughing together, seeing who hangs out with who," Kerr said. "It's great. This team has a really, really good chemistry that developed really quickly. Obviously, we had the core group intact from last year. We lost some key guys, too. The additions have been great. The chemistry is really good."

Pachulia took it upon himself to be a part of that. With constant attention on the Warriors, he knows the importance of sticking together through all of the many challenges that come in an 82-game season and those things prepare a group for the postseason.

"You wish for the chemistry to come right away because you're kind of feeling pressure, a lot of talk's going on from outside," Pachulia said. "The reality is it's a process. It takes some days, it takes some games. It takes some bumps as well for the team to get on the same page and get the chemistry right. You've got to go through the process. I just don't see it the other way. We couldn't wait for these 40 or 50 games to pass and see where we were going to be. I feel really confident where we are right now, with everything we had throughout this 50 games, even the losses we had unexpected. It made us better, it made us stronger. You can appreciate it, honestly. We care about each other. We're on the same page. Keep going. We're not going to stop."

For Iguodala and McGee, the "chatter" stays between them.

"I have a lot of really in-depth conversations with JaVale McGee," Iguodala said, "about life."

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Power of science: Warriors thrive with chemistry experiment - Daily Commercial

Explainer: What is a catalyst? – Science News for Students (blog)

(for more about Power Words, clickhere)

activation energy (in chemistry) The minimum energy needed for a particular chemical reaction to take place.

atomThe basic unit of a chemical element. Atoms are made up of a dense nucleus that contains positively charged protons and neutrally charged neutrons. The nucleus is orbited by a cloud of negatively charged electrons.

bond(in chemistry) A semi-permanent attachment between atoms or groups of atoms in a molecule. Its formed by an attractive force between the participating atoms. Once bonded, the atoms will work as a unit. To separate the component atoms, energy must be supplied to the molecule as heat or some other type of radiation.

carbonThe chemical element having the atomic number 6. It is the physical basis of all life on Earth. Carbon exists freely as graphite and diamond. It is an important part of coal, limestone and petroleum, and is capable of self-bonding, chemically, to form an enormous number of chemically, biologically and commercially important molecules.

catalyst A substance that helps a chemical reaction to proceed faster. Examples include enzymes and elements such as platinum and iridium.

catalytic converter A device made of honeycomb-shaped ceramic structures that is put onto the tailpipe of a vehicle. As exhaust gases flow through it, they encounter two different types of catalysts, each able to foster a different type of chemical reaction. One or more metals, usually platinum, rhodium, palladium and sometimes even gold coat the inside of the system. All of the walls of the devices honeycomb structure increase greatly the area of catalyst-covered surfaces now available to react with the exhaust. As the gases from the engine hit these metal coated surfaces, they break apart the pollutants, turning them into less harmful materials. A sensor in the converter also measures how much oxygen is in the exhaust. If it finds too much, it tells a computer to adjust the air-to-fuel ratio in the engine so that it will burn more cleanly.

chemicalA substance formed from two or more atoms that unite (become bonded together) in a fixed proportion and structure. For example, water is a chemical made of two hydrogen atoms bonded to one oxygen atom. Its chemical symbol is H2O. Chemical can also be an adjective that describes properties of materials that are the result of various reactions between different compounds.

chemical bondsAttractive forces between atoms that are strong enough to make the linked elements function as a single unit. Some of the attractive forces are weak, some are very strong. All bonds appear to link atoms through a sharing of or an attempt to share electrons.

chemical reactionA process that involves the rearrangement of the molecules or structure of a substance, as opposed to a change in physical form (as from a solid to a gas).

electricityA flow of charge, usually from the movement of negatively charged particles, called electrons.

engineA machine designed to convert energy into useful mechanical motion. Sometimes an engine is called a motor.

enzymesMolecules made by living things to speed up chemical reactions.

exhaust(in engineering) The gases and fine particles emitted often at high speed and/or pressure by combustion (burning) or by the heating of air. Exhaust gases are usually a form of waste.

fuel cellA device that converts chemical energy into electrical energy. The most common fuel is hydrogen, which emits only water vapor as a byproduct.

geneticHaving to do with chromosomes, DNA and the genes contained within DNA. The field of science dealing with these biological instructions is known as genetics. People who work in this field are geneticists.

hydrogenThe lightest element in the universe. As a gas, it is colorless, odorless and highly flammable. Its an integral part of many fuels, fats and chemicals that make up living tissues.

iridiumDiscovered in 1803, its name comes from the Latin for rainbow. Its a hard, brittle and corrosion-resistant metal in the platinum family. Slightly yellowish, the principle use for this element is as a hardener for platinum. Indeed, its melting point is more than 2,400 Celsius (4,350 Fahrenheit). The elements atomic number is 77.

manufacturingThe making of things, usually on a large scale.

metalSomething that conducts electricity well, tends to be shiny (reflective) and malleable (meaning it can be reshaped with heat and not too much force or pressure).

moleculeAn electrically neutral group of atoms that represents the smallest possible amount of a chemical compound. Molecules can be made of single types of atoms or of different types. For example, the oxygen in the air is made of two oxygen atoms (O2), but water is made of two hydrogen atoms and one oxygen atom (H2O).

nutrientA vitamin, mineral, fat, carbohydrate or protein that a plant, animal or other organism requires as part of its food in order to survive.

oxygenA gas that makes up about 21 percent of the atmosphere. All animals and many microorganisms need oxygen to fuel their metabolism.

palladiumA soft, ductile, steel-white, tarnish-resistant, metallic element occurring naturally with platinum, especially in gold, nickel, and copper ores.

petroleumA thick flammable liquid mixture of hydrocarbons. Petroleum is a fossil fuel mainly found beneath the Earths surface. It is the source of the chemicals used to make gasoline, lubricating oils, plastics and many other products.

plasticAny of a series of materials that are easily deformable; or synthetic materials that have been made from polymers (long strings of some building-block molecule) that tend to be lightweight, inexpensive and resistant to degradation.

platinumA naturally occurring silver-white metallic element that remains stable (does not corrode) in air. It is used in jewelry, electronics, chemical processing and some dental crowns.

pollutantA substance that taints something such as the air, water, our bodies or products. Some pollutants are chemicals, such as pesticides. Others may be radiation, including excess heat or light. Even weeds and other invasive species can be considered a type of biological pollution.

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Explainer: What is a catalyst? - Science News for Students (blog)

Detroit Pistons’ chemistry must start with Reggie Jackson – Detroit Free Press

Jamie Samuelsen, Special to the Detroit Free Press 12:06 p.m. ET Feb. 28, 2017

The Pistons' Andre Drummond, Reggie Jackson and Kentavious Caldwell-Pope celebrate a basket during the first half of the Pistons' 106-90 win Monday at the Palace.(Photo: Gregory Shamus, Getty Images)

Jamie Samuelsen, co-host ofthe "Jamie and Stoney Show"weekdays from 6-10 a.m.on WXYT-FM (97.1), blogs for freep.com. He also appears regularly on Fox 2.His opinions do not necessarily reflect those of the Detroit Free Press nor its writers. You can reach him at jamsam22@gmail.com, follow him on Twitter@jamiesamuelsen.

Is it easy to pinpoint why the Detroit Pistons haven't taken thenext step this season?

The contrast was tough to miss.

At halftime Sunday night, the Pistons retired Richard Hamiltons No. 32. It was a celebration of the manbut, more so, it was yet another celebration ofthe unique team that won it all in 2004. Coach Larry Brown beamed as he watch. Celebrating Hamilton and Chauncey Billups and Ben Wallace really has been more about celebrating that team. They played, as Brown said many times, the right way." It was a team of outcasts and second chancers who relied on each other. Those Pistons were the ultimate sum-of-its-parts team.

The current Pistons just dont seem to add up. They have talent at each position. They have talent coming off the bench. They have young guys and old guys. They have cornerstone draft picks and some second-chance guys. They have a coach in Stan Van Gundy who has reached the NBA Finals. They have all the pieces. Its just that the pieces dont quite seem tofit together.

Theres no obvious answer. If there were, Van Gundy would have found it by now. Hes a basketball junkie, and Im sure solving this puzzle has been one of the most confounding challenges of his career.

Nobody is suggesting that the Pistons are good enough to battle the Cleveland Cavaliers for the top spot in the East. But I believe they are good enough to be in the top four or five teams in the conference. The biggest problem is that the Pistons have star players who aren'tstars. Andre Drummond was an All-Star last year and earned a$127-million contract extension this summer. Reggie Jackson signed a five-year, $80-million contract in the summer of 2015 thatpays him among the top 10 point guards in the NBA. Kentavious Caldwell-Pope has been the Pistons' best player this season, just in time toget a max offer as a restricted free agent. If the Pistons dont pay him, somebody else will. I really dont want the Pistons to lose Caldwell-Pope,but Im also not sure I want to see more than $60 million next season go to a group of players withe one All-Star Game appearance between them.

The issue is chemistry. Either you have it or you dont. Hamilton and Billups seemed to have it from just about their first game together. Billups was a good shooter and had a knack for the big moment. But the bread and butter of that Pistons offense was Billups hitting Hamilton on a curl at the elbow and Rip dominating the midrange game.

For all the talk about the chemistry between Jackson and Drummond, I think the larger issue might be the chemistry between Jackson and Caldwell-Pope. Both can score. KCP is a better defender. But they dont seem to fit together quite like other guard duos in Pistons history. When you watch Ish Smith playwith Caldwell-Pope and others, there is a better flow. Smith brings the ball up knowing that hes not the primary option. Jackson doesn't.

It has been a difficult year for Jackson, whostartedthe season on the injured list and then struggledto find his game. We assumed last off-season that the Pistons would be better and that Jackson and Drummondwould lead them. Instead, the Pistons are about the same as last season, and its not clear who will lead them. KCP has hit some huge shots. He almost singlehandedly brought them back last week against Charlotte and did his best down the stretch against the Boston Celtics on Sunday night.

If Jackson is going to do his best Russell Westbrook impression and lead the team in points and assists, he has to be better. If hes going to do his best Chris Paul and facilitate others, he has to make that choice. The Pistons are somewhat married to Drummond and Jackson, barring a trade. They appear ready to get into a marriage with Caldwell-Pope, as well. Each player has strengths. Each has flaws. For the system to work, its up to Jackson to identify all of those attributes -- not just in his teammatesbut in himself.

Can he do it? The last few weeks of the regular season will be a good indicator, starting with tonight's game against Portland. The talent is here. Its up to Van Gundy to put the pieces together. And its up to Jackson to make it work.

Detroit Pistons' Ish Smith shows worth of perfect passes

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Detroit Pistons' chemistry must start with Reggie Jackson - Detroit Free Press

Shaka Smart: Texas Needs Better Chemistry To Win & Make Threes … – FOXSports.com

Texas Basketball head coach Shaka Smart says the young Longhorns team is still working on their chemistry this deep into the season.

In Mondays weekly press conference, coach Shaka Smart said some Texas players are still getting to know each other.

This especially affects shooting. The ballhandlers are still learning where their teammates want the ball and where their sweet spots are on the court.

Coach Smarts comments explain why the Horns go long stretches where the offense stagnates and the team loses confidence.

I think our teams chemistry is improving, Smart said before pausing. I think our team like a lot of teams could certainly stand to learn more and more about each other, and about what makes each other tick.

One of the things you hear about veteran teams is Hey, weve played together for a while. We know where this guy likes the ball, or what this guys tendencies are.

I mean, Andrew Jones and Jarrett Allen are just starting to get to know each other. Those are two guys playing better than anyone else on our team. Thats just one example. I think those guys certainly have a better chemistry together than they did two, three months ago.

With the Texas Longhorns near the bottom of the Big 12 at 4-8 in the conference, Shaka Smart is looking for more group effort. He said they do not have an individual leader to run the show, like incoming freshman Matt Coleman could be next year.

So, the game strategy is for all five guys on the court to play together as a unit. But, without that strong team chemistry, the Horns have been inconsistent throughout the year. This is especially the case on the road, where Texas has not won all season.

Coach Smart also spent a lot of time on Monday talking about the teams outside shooting woes, which is the result of the chemistry issue.

Through Saturdays game, the Texas Longhorns arelast in the Big 12 in three-point shooting. Texas is only shooting .296, which is not even close to next-to-last TCU at .340.

Texas is only making 5.7 three-pointers per game, which is nearly one full shot behind next-to-last Oklahoma at 6.5 made threes per game.

Another concerning stat is that Texas is #340 out of all 351 college basketball teams in three-point shooting. Also, Texass 5.7 makes per game ranks #320.

Feb 1, 2017; Austin, TX, USA; Texas Longhorns guard Eric Davis Jr (10) shoots for three to take the lead in the final minute against the Texas Tech Red Raiders during the second half at the Frank Erwin. The Longhorns won 62-58. Mandatory Credit: Brendan Maloney-USA TODAY Sports

Shaka Smart said players have to set up other players, and the shooters need to carry over their technique. But, with an individual mindset, some players lose focus on the task at hand.

The two outside shooters that Smart wants to see become more consistent are Jacob Young and Eric Davis. The freshman Young is a great rhythm shooter in practice, but hes still learning about a different rhythm in live game situations.

Smart emphasized that all the shooters need to shoot the right way, with discipline and confidence. But, for Young, its been a real challenging stretch for him because hes an excellent shooter in controlled environments.

But, until the Texas Longhorns develop a strong team mindset on the court, the team will continue to struggle to shoot and win on the road.

Their next chemistry test is Tuesday night in Norman when they face last-place Oklahoma in a rivalry game. Will the lessons from past road strugglesfinally turn intoa win away from Austin? Coach Smart hopes to see that, plus a few more three-point shots go down.

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Shaka Smart: Texas Needs Better Chemistry To Win & Make Threes ... - FOXSports.com

Team chemistry has improved 3-point shooting, Kings say – Sacramento Bee


Sacramento Bee
Team chemistry has improved 3-point shooting, Kings say
Sacramento Bee
Guard Darren Collison seemed surprised when told the Kings' 18 3-pointers in a win over the Atlanta Hawks on Friday night set a franchise record. Especially with all the shooters that's been through this organization, Collison said. You think about ...

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Team chemistry has improved 3-point shooting, Kings say - Sacramento Bee

Newly Created Helium Compound Could Completely Change … – Futurism

Noble Gases

Noble gaseshelium, neon, argon, krypton, xenon, and radonhave long been believed to be the least reactive elements on the periodic table. Heliums composition in particular, with its full outer electron shell, makes it theoretically unable to interact with other atoms to form a stable compound. So while other noble gases like xenon, krypton, and radon have successfully reacted to create compounds under extreme pressure, helium has thus far been incapable.

However, despite the assumed impossibility, a team of international scientists has recently created a stable helium-sodium compound.

Chemistry changes when you apply high pressure, and this can be achieved inside our Earth and on different planets like Saturn, said Ivan Popov from Utah State University in an interview with Gizmodo. But this is a book changer.

In previous attempts of pairing helium with other elements, results have always been fleeting. Heliums closed shell configuration makes it difficult, if not downright impossible, for the element bond with other atoms. But this restriction is tied to the assumption that conditions are the same or similar to those on Earths surface. In outer space, its very possible that heliums ability to react is very different given the change in environment.

[E]xtremely high pressure, like that found at Earths core or giant neighbours, completely alters heliums chemistry, adds Utah State researcher, Alex Boldyrev told Phys.org.

To test this theory, the team used a crystal structure predicting computer model in which they could observe how helium would react under extreme pressure. By exposing helium and sodium to atmospheric pressure 1.1 million times more than Earths, they were able to create the compound Na2He.

This compound, along with breaking the rules of Heliums reactivity, it also didnt bond in a typical way. The cubic arrangement of alternating sodium and helium atoms isnt held together by chemical bonds. According to Boldyrev, when we performed chemical bonding analysis of these structures, we found each empty cube actually contained an eight-center, two-electron bond This bond is whats responsible for the stability of this enchanting compound. Helium changes the interaction between sodium atoms so much that if it is removed, the entire structure becomes unstable.

Because it challenges long-standing assumptions about modern chemistry, experts are quick to note that this study has yet to be supported by or replicated in independent experiments that deliver the same, or similar, results. This means that more studies will have to be conducted to fully understand and validate the breakthrough this particular team has uncovered.

This curious discovery implies that there might not be a lot of applications on Earth. Essentially, the results were derived from following altered scientific rules and very extreme conditions, which we wouldnt naturally find on this planet. But environments similar to what was created in this experiment, like the center of gas giant planets like Jupiter and Saturn where helium abounds, provide a context for these reactions that offer insight into how chemistry works on other planets.

It also raises a lot of questions about our understanding of chemistry. Our benchmark for chemical reactions is derived from our knowledge of this world. With the impending possibility of long-term space travel on the horizon, we have to be open to the fact that chemistry as we know it is not always the way that we know it.

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Newly Created Helium Compound Could Completely Change ... - Futurism

Quick: Chemistry Key To Passing Game – Philadelphia Eagles – PhiladelphiaEagles.com

Establishing a consistent passing game at the NFL level is like creating a work of art. Its a mix of different ingredients coming together in the right way to create something special.

In the Eagles offense, timing is key when it comes to the passing game. Some have called Doug Pederson and Frank Reichs offense a West Coast hybrid, and one of the fundamental features of that offense is timing. It needs to be just right, or the finished product doesnt come out the way it was drawn up and mapped out.

How is that timing developed? According to Mike Quick, who played nine seasons with the Eagles and is in the team's Hall of Fame, it all comes down to a quarterback being able to build and improve upon a relationship with his wide receiver. Thats not something that typically happens overnight.

Theyve got to spend time together, Quick said on a recent episode of the Eagle Eye in the Sky podcast with Fran Duffy. To me, thats the bottom line because (Wentz) has to know them. ... Once he has the time to spend with those guys, then the passing game is going to be completely different. That back-shoulder throw is such a big tool now in the NFL. When a guy is taking away from you getting to the up-field shoulder and you have to make the back-shoulder throw, it comes from a lot of repetition and it comes from timing of knowing where to place the ball so your receiver can stop, adjust to the football, and make a play on it. ... All of these things come in time.

In Quicks estimation, an increase in chemistry will only help to add another dimension to the Eagles passing offense. One of the areas where the Eagles struggled in 2016 was in taking deep shots down the field. Bryce Treggs added more of a vertical threat after getting on the field around midseason and Nelson Agholor hauled in a 40-yard touchdown pass in the Week 16 game against New York, but the Eagles never developed a consistent down-the-field passing game.

That could change in 2017, says Quick.

One of the areas where the Eagles need to get better at next year, Fran, is throwing the ball down the field. I was asked about Carson Wentz being a guy whos 6-foot-5 and how he gets a lot of balls batted down. Well, when youre throwing the ball 10 yards down the field the majority of the time, thats going to happen because teams understand that your trajectory is low and its not going to be as high as when youre throwing the ball down the field. They know that theyll have chances to hit the ball.

They have to throw the ball down the field, and Carson has to get used to these guys know their gait, know the timing, know how far he can lead a guy, and just how far he can put a ball out in front of a guy and how he can go and get it. Thats different for all of his guys, and the more he spends time with the guys, the more he understands them, understands how they speed up after they stop or getting off of pressure.

Quick also noted that theres not really a set amount of time that it takes for a quarterback to become adjusted to his group of receivers. For Quick, his big jump came in his second season. He was able to turn things around after catching just 10 passes his rookie year.

Theres no exact answer, Quick explained. Youll start to feel it. Its like a non-verbal communication thing. Youll start to feel it in time with your quarterback and he understands you and you understand him. For me coming into the league, it was as early as my second year working with (Ron) Jaworski. My first year was a strike-shortened year. We took a lot of time in playgrounds and high school fields in the area, just throwing it around and getting to know each other, and it started to click.

When Randall (Cunningham) came in as the quarterback, some years later, it took a little bit longer, but it starts to click at some point. That non-verbal communication sets in and you start to understand the guy. You understand just by his movements what hes going to do, and thats going to happen for these guys.

Shortly after the regular season ended, Howie Roseman expressed how the goal moving forward is to find the right pieces to build around Wentz and help him develop into an elite quarterback. The Eagles will certainly look to upgrade the wide receiver position during this offseason, as they will do with every position group, but Quick believes that the season Wentz spent with some of his returning weapons will be huge for his development moving forward.

I think Jordan (Matthews) has a good relationship with Carson already, and I think the relationship with Zach Ertz is really improving and you could really see that over the last quarter of the 2016 season, that theyre really improving in their relationship and their non-verbal communication, Quick said. Thats going to be key. As he spends more time with these guys, hell start to understand them better.

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Quick: Chemistry Key To Passing Game - Philadelphia Eagles - PhiladelphiaEagles.com

One former UCLA champion recognizes current team’s chemistry – Los Angeles Times

Tyus Edney has seen this all before.

The early season victory over highly ranked Kentucky. A feisty sixth man point guard. Freshmen who changed the complexion of the team. A disheartening road loss to Oregon for the first defeat of the season followed by an emotional home triumph over the Ducks.

The onetime dynamo of a point guard would like another similarity to emerge between two of the most enthralling UCLA teams in recent decades: the ending.

The 1994-95 season concluded with Edney and his teammates cutting down the nets inside Seattles Kingdome after winning the national championship. The current Bruins are in the midst of another potentially magical journey, which continues Sunday afternoon against Oregon State at Pauley Pavilion.

Scoring was not an issue for either team, which routinely topped 90 points. They also both thrived in the fun department.

The key with our team was we genuinely enjoyed making plays for each other and helping somebody get a dunk or a layup or anything, getting stops on defense, said Edney, a senior on UCLAs last championship team who returned in 2010 as director of operations. We loved that stuff and it was genuine and we were as close off the court as on the court, and I think thats a quality of this team, just how they get along off the court and it shows on the court.

Like the present team, Edneys Bruins featured a group of last-chance seniors who welcomed freshmen who could help them reach places they could not getalone. Newcomers Toby Bailey, J.R. Henderson and Kris Johnson created a winning blend alongside seniors Edney, Ed OBannon and George Zidek.

Our freshmen coming in elevated our game to another level, Edney said.

The same sentence applies to UCLA freshmen Lonzo Ball, TJ Leaf and Ike Anigbogu, who have provided the support that seniors Bryce Alford and Isaac Hamilton lacked last season on the way to a losing record.

Balance was a trait of both teams. Four Bruins scored at least 20 points in a game last week against Washington for the first time in the programs history since you guessed it Edney and the 1994-95 team did it against George Mason.

His team has a lot of comparisons to this team, Alford said recently. Its almost eerily similar how its been so far.

The first player off the bench on Edneys team was usually Cameron Dollar, a sophomore point guard who has a contemporary counterpart in Aaron Holiday. Dollar saved the Bruins with a gritty performance in the national championship game against Arkansas after a sore wrist limited Edney to less than three minutes.

UCLA lost only two games that season, but the record book shows them finishing 32-1 because a setback against California later became a victory as a result of NCAA violations committed by the Golden Bears. The Bruins beat then-No. 3 Kentucky in late November and rose to No. 1 in the rankings after a victory over Duke in late February.

Their NCAA tournament run is largely remembered for Edneys mad dash with 4.8 seconds left that resulted in a buzzer-beating layup to topple Missouri in the second round. Ball might be even more of a blur.

Hes fast, like I think I was pretty fast, Edney said, but I considered myself an unselfish guard, too, and I enjoyed making plays for our guys and I see that about him, that he really does make people better and he likes making plays for guys and hes smart, hes a good player, he knows how to play the game.

The present-day Bruins like it whenever Edney tells them about the great old days for a program experiencing a 22-year title drought. Alford said he tries to learn something from his predecessor every day.

Hes been a huge part of what were doing so far this year, our success, Alford said, and hes going to continue to kind of be that guide this year for our team and our guys of how we can get to where we want to go.

::

UP NEXT

VS. OREGON STATE

When: 2 p.m., Sunday

Where: Pauley Pavilion.

On the air: TV: FS1; Radio: 570.

Update: UCLA would receivea No. 4 seeding in the NCAA tournaments East Regional if the season ended Saturday, according to a sneak peek of the brackets revealed by the selection committee. Of course, theres a month to go before the only brackets that matter are released. The 10th-ranked Bruins (22-3 overall, 9-3 Pac-12 Conference) probably wont budge from their spot Sunday unless they lose to the Beavers (4-21, 0-12), who have dropped 12 consecutive games and may not get leading scorer Tres Tinkle back this season from the broken right wrist that has sidelined him since late November.

ben.bolch@latimes.com

Twitter: @latbbolch

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One former UCLA champion recognizes current team's chemistry - Los Angeles Times

Database for chemical reactions updates to improve R&D exchanges – Drug Target Review

The newest version of the Unified Data Model (UDM) project has been released, allowing R&D scientists to access information on compound synthesis and testing.

The latest file format of theUnified Data Model (UDM) has been released by the Pistoria Alliance, a global, not-for-profit organisation. According to the alliance, this update delivers a stable foundation for the collection and exchange of chemical reaction data and empowers the R&D community to move forward with its adoption.

The release is built upon standard (Allotrope-compatible) vocabularies for units of measure and analytical methods, allowing the systems to be interoperable. The alliance emphasises that as increased adoption of artificial intelligence (AI) and machine learning (ML) in R&D continues, industry-wide data standards are essential in the move towards the digitally driven Lab of the Future (LoTF).

The latest update of the UDM seeks primarily to improve the semantics and validation of data. Without alignment on terms and data models, great opportunities to see trends or wider patterns are missed, says the organisation. Standardised harmonisation of data is especially important in this time of increased AI, ML and deep learning use, which are reliant on high quality data to improve outcomes and predictions.

This most recent version has been supported by funding from Biovia, Elsevier, GlaxoSmithKline (GSK), Novartis, Roche and Bristol-Myers Squibb (BMS).

The latest update of the UDM seeks primarily to improve the semantics and validation of data

The UDM is exactly the type of essential project the Pistoia Alliance was formed to work on it enables internal and external collaboration and ultimately helps to accelerate innovation and discovery, commented Dr Steve Arlington, President of the Pistoia Alliance. Following this latest update, the project is now shifting into a support phase to help companies adopt the UDM model. Most recently we have secured additional funding from BMS to allow us to continue the project to benefit users and we are pleased to welcome Cynthia Beno from BMS to our steering committee. We are also currently looking for additional funding in order to develop a toolkit which would bring together methods, techniques and literature to support the adoption of the UDM.

At Roche, we are very excited to continue to be involved in the UDM project and we recognise its value to the research community, commented Brian Jones, Principal Scientist of Discovery Informatics at Roche and UDM Project Champion. It is great to have progressed the UDM to this stage and to now move to supporting and promoting the adoption of the model.

Its fantastic to see the UDM continue to develop under the project teams stewardship and to serve the R&D ecosystem. Elsevier donated the original UDM to the Pistoia Alliance and we hope it continues to succeed and promote collaboration in the future, commented Tim Hoctor, Vice President of Professional Services at Elsevier and board member of the Pistoia Alliance.

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Database for chemical reactions updates to improve R&D exchanges - Drug Target Review

Twins are proof that MLB teams once again value character and … – FOXSports.com

The Twins signing of free-agent left-hander Craig Breslow to a minor-league contract on Wednesday hardly qualified as a major move. But the Twins had the same idea when they recently tried to pull off something bigger the addition of free-agent first baseman Mike Napoli.

In each case, the Twins wanted the player not only for what he might contribute on the field, but also what he might add off of it. And while they failed to land Napoli even after offering him more money than the Rangers, according to major-league sources the teams new front office has made it clear that it values the intangible as well as the tangible.

Talent is an aspect of any decision we make, said the Twins chief baseball officer, Derek Falvey. But there is an element of clubhouse chemistry that also plays a role in organization-building. Were going to talk about leadership, makeup and how guys fit in our clubhouse along with how we feel they will perform.

Napoli, according to major-league sources, agreed to a one-year, $8.5 million deal to return to the Rangers, for whom he played in 2011-12 and 15. Familiarity, however, was not his only consideration. The Rangers are more likely to contend than the Twins, and Napoli, 35, has appeared in eight of the last 10 post-seasons, including World Series with three different clubs.

With the Twins, Napoli likely would have alternated with Joe Mauer at first base and designated hitter, helping fill the leadership void that the team experienced when outfielder Torii Hunter retired after the 2015 season.

Falvey recently hired three high-character former Twins Hunter, Michael Cuddyer and LaTroy Hawkins as special assistants to the baseball operations department. Hunter was teammates with Napoli with the Angels from 2008 to 10.

Some de-emphasized chemistry in the early years of the analytics revolution, but that trend appears to be reversing. Both of last years World Series participants the Cubs and Falveys previous employer, the Indians value makeup. Even the Athletics, a team that once was dismissive of chemistry, have talked about giving greater consideration to a players character.

Breslow, a 12-year veteran who has lowered his arm slot in an effort to revive his career, said he took less money from the Twins than other clubs offered because of the chance to lead and help with the teams rebuilding program.

The thing that resonated the most with me was the idea that I could impact the culture and impact the direction of the organization for longer than potentially my stay there might be, Breslow said.

Derek is a really engaging and bright guy with a great vision for the organization. Ive got no doubt that hell be able to be able to bring sustained success. The opportunity to be part of that at this stage of my career is one that is really compelling.

Richard Mackson | USA TODAY Sports

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Twins are proof that MLB teams once again value character and ... - FOXSports.com

As the Lakers build chemistry, LeBron James works to keep the temperature down – The Athletic

It really was just one game. The first of 82, against a projected defensive juggernaut and the consensus title favorite. And its not like the Lakers got run off the court in their 112-102 loss to the Clippers on Tuesday.

But one game could very easily become two on Friday against the Utah Jazz, a team expected to contend for a top seed in the Western Conference. And even with a relatively soft early season schedule, two could become more faster than some media and many (most?) fans might have expected.

In this city with this team two superstars, championship expectations, intense scrutiny and a coaching staff constructed to promote palace intrigue (during the game, I couldnt resist my own tongue-in-cheek-but-undeniably trollish Tweet on the Frank Vogel/Jason Kidd dynamic) thats enough to very quickly crank the amps up to 11.

Its why LeBron James wisely went hard on process and context following Tuesdays loss,...

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As the Lakers build chemistry, LeBron James works to keep the temperature down - The Athletic

Chemists Glimpse the Fleeting Transition State of a Reaction for the First Time – SciTechDaily

MIT chemists have devised a way to observe the transition state of the chemical reaction that occurs when vinyl cyanide is broken apart by an ultraviolet laser. Credit: Christine Daniloff, MIT

During a chemical reaction, the molecules involved in the reaction gain energy until they reach a point of no return known as a transition state.

Until now, no one has glimpsed this state, as it lasts for only a few femtoseconds (quadrillionths of a second). However, chemists at MIT, Argonne National Laboratory, and several other institutions have now devised a technique that allows them to determine the structure of the transition state by detailed observation of the products that result from the reaction.

Until now, no one has glimpsed this state, as it lasts for only a few femtoseconds (quadrillionths of a second).

Were looking at the consequences of the event, which have encoded in them the actual structure of the transition state, says Robert Field, the Robert T. Haslam and Bradley Dewey Professor of Chemistry at MIT. Its an indirect measurement, but its among the most direct classes of measurement that have been possible.

Field and his colleagues used millimeter-wave spectroscopy, which can measure the rotational-vibrational energy of reaction product molecules, to determine the structure of the products of the breakdown of vinyl cyanide caused by ultraviolet light. Using this approach, they identified two different transition states for the reaction and found evidence that additional transition states may be involved.

Field is the senior author of the study, which appears this week in the Proceedings of the National Academy of Sciences. The lead author is Kirill Prozument, a former MIT postdoc who is now at Argonne National Laboratory.

For any chemical reaction to occur, the reacting molecules must receive an input of energy that enables the activated molecules to reach a transition state, from which the products are formed.

The transition state is a central concept of chemistry, Field says. Everything we think about in reactions really hinges on the structure of the transition state, which we cannot directly observe.

In a paper published in 2015, Field and his colleagues used laser spectroscopy to characterize the transition state for a different type of reaction known as an isomerization, in which a molecule undergoes a change of shape.

In their new study, the researchers explored another style of reaction, using ultraviolet laser radiation to break molecules of vinyl cyanide into acetylene and other products. Then, they used millimeter-wave spectroscopy to observe the vibrational level population distribution of the reaction products a few millionths of a second after the reaction occurred.

Using this technique, the researchers were able to determine nascent populations of molecules in different levels of vibrational energy a measure of how much the atoms of a molecule move relative to each other. Those vibrational energy levels also encode the geometry of the molecules when they were born at the transition state, specifically, how much bending excitation there is in the bond angles between hydrogen, carbon, and nitrogen atoms.

This also allowed the researchers to distinguish between two slightly different products of the reaction hydrogen cyanide (HCN), in which a central carbon atom is bound to hydrogen and nitrogen, and hydrogen isocyanide (HNC), in which nitrogen is the central atom, bound to carbon and hydrogen.

This is the fingerprint of what the structure was during the instant that the molecule was released, Field says. Previous methods of looking at reactions were blind to the vibrational populations, and they were blind to the difference between HCN and HNC.

The researchers found both HCN and HNC, which are produced via different transition states, among the reaction products. This suggests that both of those transition states, which represent different mechanisms of reaction, are in play when vinyl cyanide is broken apart by the ultraviolet laser.

This implies that there are two different mechanisms competing for transition states, and were able to separate the reaction into these different mechanisms, Field says. This is a completely new technique, a new way of going to the heart of what happens in a chemical reaction.

The new technique allows scientists to explore the transition state in a way that has previously not been possible, says Arthur Suits, a professor of chemistry at the University of Missouri.

In this work, the researchers use the powerful new technique of broadband rotational spectroscopy to monitor the nascent vibrational distributions of the products of a photodissociation reaction, thereby gaining deep insight into two different transition states, says Suits, who was not involved in the study. Broadband rotational spectroscopy continues to amaze us with unexpected applications such as this glimpse of the elusive transition, and other exciting advances driven by this technique are no doubt on the way.

The researchers data shows that there are additional reaction mechanisms beyond those two, but more study is needed to determine their transition state structures.

Field and Prozument are now using this technique to study the reaction products of the pyrolytic breakdown of acetone. They also hope to use it to explore how triazine, a six-membered ring of alternating carbon and nitrogen atoms, breaks down into three molecules of HCN, in particular, whether all three products form simultaneously (a triple whammy) or sequentially.

The research was funded by the Department of Energy, the Petroleum Research Fund, and the National Science Foundation. Other authors of the paper include Joshua Baraban PhD 13 of Ben-Gurion University; G. Barratt Park PhD 15 of the Max Planck Institute for Biophysical Chemistry; Rachel Shaver SM 13; P. Bryan Changala of the University of Colorado at Boulder; John Muenter of the University of Rochester; Stephen Klippenstein of Argonne National Laboratory; and Vladimir Chernyak of Wayne State University.

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Chemists Glimpse the Fleeting Transition State of a Reaction for the First Time - SciTechDaily