Crystals reveal the site of the world’s oldest meteorite strike – Chemistry World

Chemical analysis of ancient crystals has revealed a meteorite strike in Australia 2.229 billion years ago is the oldest impact yet discovered.1

The meteorite hit when our planet was covered in ice, and researchers think a cloud of water vapour it threw into the atmosphere could have acted as a greenhouse gas to warm the entire planet.

The researchers studied crystals they sampled in 2014 at the Yarrabubba impact site in Western Australia, about 620km north-east of Perth.

The impact is thought to have been caused by a roughly 7km meteorite smashing into the Earth, but its heavily-eroded 70km crater is now only visible as a central anomaly in geophysical surveys, and almost nothing can be seen on the surface.You are right in the Australian bush, it is kind of what you imagine kangaroos and emus running past, a very flat, desert-like landscape, says study co-author Chris Kirkland, a geochronologist at Curtin University in Perth.

Kirkland and his colleagues imaged tiny grains of zircon and monazite, smaller than the width of a human hair, to see where their crystal structures were deformed by the meteorite impact. The individual grains are actually quite beautiful, he says. Theyve got a range of textures that can only be produced under extreme temperature and pressure conditions and the only way to get those extreme temperatures and pressures on Earth is to slam a large rock into another large rock.

Zircon and monazite contain traces of uranium, so the researchers used a narrow beam of oxygen ions to measure radioactive decay products in the parts of the grains deformed by the meteorite impact. By targeting the specific domains within the crystals that were reset by the impact event, we were able to get the age of the impact, explains lead author Timmons Erickson, a geochronologist at Nasas Johnson Space Center at Houston in the United States.

The impact 2.229 billion years ago is 200 million years older than the Vredefort Dome in South Africa, the next oldest-known meteorite crater.

It coincides with the end of a period of intense glaciation a so-called snowball Earth state and raises the possibility that the Yarrabubba meteorite was the reason it ended. The impact could have melted an ancient layer of ice and released up to 5 trillion tonnes of water into the atmosphere eventually tipping the chemistry of the earths atmosphere so it could sustain the warm conditions of today, Erickson says.

Kenneth Amor, a geochemist at the University of Oxford, says the dating of the impact by Erickson and colleagues looks believable. Amor was not involved in the research, but he recently led a team that discovered the largest meteorite to hit Britain a 1.2 billion year-old impact in Scotland.

The idea that a cloud of water vapour from Yarrabubba warmed the Earth is an interesting one, he says. But if the effects only lasted a few years it would be unlikely to result in a glacial thaw, unless that thaw was already underway.

While the study led by Erickson has identified the oldest-known meteorite impact, another study has found the worlds oldest substance inside a meteorite that fell in 1969.2 By measuring neon isotopes created by exposure to cosmic rays, the researchers determined some silicon carbide grains in Australias Murchison meteorite formed up to 7.5 billion years ago long before our sun and planets.

The international team thinks that the grains were part of the interstellar dust that coalesced to form our solar system about 5 billion years ago.

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Crystals reveal the site of the world's oldest meteorite strike - Chemistry World

Deadly Gessner explosion the latest in string of major chemical incidents for Houston area – Houston Chronicle

It's a scene that's all too familiar to Houston residents.

Explosions, flames reaching into the sky, plumes of black smoke, calls to shelter in place, evacuations, injuries and deaths.

The explosion early Friday morning at a manufacturing plant was the latest deadly reminder of the potential danger posed by hazardous material facilities in the Houston area.

In 2019, there were at least five major chemical incidents in Southeast Texas.

STAY INFORMED: Subscribe to the Houston Chronicle for complete local news coverage.

On March 16, a tube leak caused a fire at Exxon Mobile's Baytown facility. The fire sent thick clouds of dark smoke into the sky. The company reported releases of sulfur dioxide, hydrogen sulfide and benzene for more than a week after the blaze.

The next day, an equipment failure at International Terminal Company's chemical tank farm in Deer Park caused a fire that burned for three days. The fire shut down the Houston Ship Channel, released large amounts of pollution into the air and water and led to multiple shelter-in-place orders for the surrounding communities.

On April 2, a transfer line carrying isobutylene ignited at the KMCO chemical facility in Crosby. The resulting explosion killed one worker and injured more than 30 others. The explosion reduced the building at the epicenter of the blast to shrapnel.

'I WAS SHOOK': Residents recall hearing massive warehouse explosion in west Houston

Shortly before the Thanksgiving holiday, an enormous explosion at TPC Group's facility in Port Neches injured workers and damaged homes. Fires in the aftermath burned for a week and led to evacuations of thousands of residents. One fatality

The Houston area is home to more than 2,500 chemical facilities.A 2015 Houston Chronicle investigation found there was a major chemical incident in the greater Houston area every six weeks.The investigation found many facilities posed serious threats to the public but were unknown to most neighbors and largely unpoliced by government at all levels.

In November, the Trump administration rolled back a number of chemical safety regulations created in response to the 2013 West Fertilizer explosion that killed 15 and injured more than 200. A coalition of environmental groups sued to stop the rollback.

With those regulations off the books, companies will not have to complete third-party audits or a root-cause analysis after an incident. Companies also will not have to provide the public access to information about what type of chemicals are stored in these facilities either.

While the federal government weakened regulations, Harris County has taken a more aggressive stand with the petrochemical industry in recent months. The county brought civil lawsuits and criminal charges to multiple chemical companies after incidents in 2019. This has led to a race to the courts as the state and the county fight over taking the lead in penalizing polluters.

TRY THE APP: Get alerts, breaking news and in-depth coverage on what's happening in Houston for your mobile phone and tablet devices through our mobile apps on Google Play and the App Store.

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Packers QB Aaron Rodgers explains chemistry with Jordy Nelson – Packers Wire

Even during OTAs, Aaron Rodgers and Jordy Nelson are capable of producing the wow play for the Green Bay Packers.

During a team drill on Tuesday, Rodgers and Nelson delivered one of those special plays with Rodgers threading the needle between two defenders and Nelson contorting his body to get two feet inbounds along the back of the end zone for the score.

The chemistry between Rodgers and Nelson remains inextinguishable.

We know each other on the field really well, Rodgers said on Tuesday. He understands when the balls coming out, where he needs to be in certain spots. Weve done so many things in practice over the years. Hes always seeing the game through the quarterbacks eyes. He knows timing and spacing and second and third reactions better than anybody thats ever been here.

Even after Nelson missed the entire 2015 season with a knee injury, the connection between quarterback and receiver never suffered. Rodgers found Nelson for 97 completions and 1,257 yards in 2017, with 14 of the connections ending in touchdowns. No other quarterback and receiver combined for more last season.

How do two players so in sync get better during a June practice? Rodgers said the key is always working to build the chemistry.

Its just continuing to try and stay on the same page with him, and build, Rodgers said. Every season hes been healthy, weve had some pretty big years.

The numbers are undeniable. Over his last five healthy seasons, Nelson has produced 397 catches, 6,098 yards and 57 touchdowns with the majority of the production coming from the right arm of Rodgers. He also has four seasons with at least 1,200 yards and three with 12 or more touchdowns.

Rodgers and Nelson will enter their ninth season together in 2017. The chemistry between quarterback and receiver remains as strong as ever.

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Packers QB Aaron Rodgers explains chemistry with Jordy Nelson - Packers Wire

The color of organic chemistry and a meaty structure mistake – Chemical & Engineering News

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Smart kid: Coloring an introduction to chemicals.

Credit: Neil Garg

When his daughter Kaylie was four, University of California, Los Angeles, chemistry professor Neil Garg noticed a disturbing trend: She was scared of chemicals.

I would give her something new, and she would say, Is that a chemical? Garg remembers.

So Garg set out to help Kaylie and her older sister, Elaina, understand that chemicals are vital to some of their favorite things. Because they love to color, he thought a coloring book might be the perfect vehicle to spread that message to his girls and other kids their age.

Garg involved Elaina and Kaylie in creating The Organic Coloring Book, starting with deciding which chemicals to present. We came up with the chemicals that they were curious about, he says.

The family started with a chemical question, such as Whats a chemical that makes soap so foamy? Then they determined the chemical answer, presented in the book as a structure. I really liked making the chemical questions. I thought that was fun, Elaina tells Newscripts. Coming up with the chemical answers was cool too.

Elainas favorite chemical is dimethylpyrazine, which is a vital part of bacons smell. Kaylies is the cyanidin that colors blueberries, one of her favorite foods.

Garg hired a graphic designer to draw the book based on structures provided by Garg and several of his graduate students. Although the structures are in two dimensions on the page, he has been happy with how well his kids and others understand what they are seeing. Its not too far from the creative imagination of a kid to understand what it looks like in 3-D, he says.

The designer came up with the idea of introducing an animal that guides readers through the book, named Cheesy the Mouse. Dressed in a lab coat, Cheesy introduces readers to the various chemical questions and answers. Kaylie chose a mouse guide because I like mice and they love cheese.

For 1-sulfinylpropane, Cheesy cries as she shows how the chemical in onions makes your eyes sting. Our eyes make tears to wash the chemical away, Cheesy explains.

The coloring book has sold about 100 copies via Amazon.com already, and the family has given them away at both girls schools.

The book should attract parents who are interested in teaching their kids about how the world works. Its really something for kids to at least get exposed to chemicals, Garg says.

Oscar Mayer oops: The meat maker is correcting this ad campaign that showed mistakes in several chemical structures.

Credit: Twitter

The advertising department at Oscar Mayer could have used a coloring bookor other guidance from chemistson its recent advertising campaign.

The company made the exciting announcement that it had removed all nitrites and nitrates from its hot dogs. But its television ad flipped the two structures, causing a minor uproar on Twitter. Hey @oscarmayer, if you have any chemists working for you, have them review your commercials before they air, @ChemMarketeer tweeted.

The ad features another chemical mistake just a few seconds later: A structure labeled artificial preservatives includes an aromatic ring with its double bonds in all the wrong places.

Spokesperson Lynne Galia of Kraft Heinz, which owns Oscar Mayer, tells Newscripts they are aware of the issue. The structures have been corrected and will be reflected in the ads on air soon, she says.

If they need more help, they might be able to call Elaina and Kaylie Garg.

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The color of organic chemistry and a meaty structure mistake - Chemical & Engineering News

In a test of Boston Celtics team chemistry, Kemba Walker & Jaylen Brown show just how different things are – MassLive.com

BOSTON -- Kemba Walker was cooking.

Its the type of cooking weve seen before. Its the type that destroyed the Celtics in Charlotte at the end of last season, erasing an 18 point fourth quarter Boston lead in a blink.

Its the type that earned him the nickname Cardiac Kemba.

With the Celtics down seven in the fourth quarter, he hit a pull up jumper.

30 seconds later, after a Toronto Raptors turnover, Walker hit a 3-pointer to cut it to two.

20 seconds later, after Pascal Siakam finally missed a shot, Jaylen Brown pulled up and missed from 18 feet.

Wait, what?

Everyone in the building knew at that moment it was the wrong shot to take. Brad Stevens was demonstrably upset. When Norm Powell drew a foul and went to the line to calmly stop the Walker onslaught, Brown looked at Walker to give him the my bad.

Walker didnt want to hear it.

He dont have to apologize to me. Hes not a bad guy, he works hard, Walker said after the game. He took a great shot, he just missed. I didnt want him to apologize. I wanted him to be confident.

Its a moment that might not have existed in a different time. Brown, standing in the lane as Powell shot, looked at Walker who was waving his arms like an NFL ref signaling an incomplete pass. The play, Walker was telling Brown, was over.

He told me I was good, Brown said after the game. Brad had an aneurysm and Kemba was like, Youre good, bro. Just keep playing.

And keep playing, he did.

As Kemba resumed ripping the hearts out of the Raptors, Brown pitched in with a monster weak-side block, a layup, and a gorgeous three-quarter court bounce pass to Gordon Hayward on the fast break. Hed later add another block and a 3-pointer to help seal the win.

I loved (Browns) reaction, Stevens said of the free throw line exchange. He knew. And I loved Kembas reaction. Both of those guys reacted great. Thats what its all about.

It really was a record scratch kind of moment. In a way, it was one of the first tests of the teams chemistry. We were finally getting to see if all the team building in China and rah-rah preseason positivity was real or just some fluffy storyline.

Here they were, in the home opener, one game after the teams new superstar laid an egg on the road. He was finally cooking. He was hearing it from the crowd, soaking it all in, leading a big comeback. And then a guy, one of last years young guys, in fact, took that shot.

It could have gone differently.

Its great for me just to know that he has your back because you dont always have that case or that scenario, Brown said after the game. Easily somebody could have said something or got upset or thrown a tantrum or whatever, but Kemba was like, No, youre good. Just play. It was the confidence I needed to make sure the next play was the right play.

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In a test of Boston Celtics team chemistry, Kemba Walker & Jaylen Brown show just how different things are - MassLive.com

MAFS’ Anthony D’Amico on His ‘Great Chemistry’ with Ashley Petta: ‘She’s an Absolute Knockout’ – PEOPLE.com


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MAFS' Anthony D'Amico on His 'Great Chemistry' with Ashley Petta: 'She's an Absolute Knockout'
PEOPLE.com
Married at First Sight is back! On season 5 of Kinetic Content's hit social experiment show, three couples meet for the first time at the altar just minutes before exchanging vows. The newlyweds (whose wedding portraits were taken by Mike Staff ...

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MAFS' Anthony D'Amico on His 'Great Chemistry' with Ashley Petta: 'She's an Absolute Knockout' - PEOPLE.com

Predicting which undergrads will succeed in chemistry – Chemistry World (subscription)

Researchers at Washington University in St Louis have examined cognitive differences in university students that may contribute to their high dropout rate from introductory undergraduate chemistry courses. They found that those who can make accurate extrapolation predictions based on concepts presented in class what they dub abstraction learners consistently outperformed so-called exemplar learners who have trouble doing so and instead depend on rote memorisation. These performance differences were even more pronounced for those enrolled in higher level organic chemistry courses.

The Washington University team studied more than 800 students taking chemistry courses over three semesters at a highly competitive US research university, roughly half of whom were classified as having difficulty bridging the gap between a concept and an illustrative example. The researchers used a learning assessment to determine how well these students understood abstract concepts presented during a fictional assignment that required them to learn the functional relation between two new elements associated with a new organism supposedly discovered on Mars.

The researchers found that active learning, at least in the form of a peer-led approach, helped a subset of the exemplar learners perform better. To determine whether these results are replicated in other introductory scientific courses and at other research institutions, the researchers are studying these effects in other science, technology, engineering and mathematics (Stem) classes and at different universities.

Tools to anticipate which students might have difficulty in chemistry and other science subjects are helpful as poor grades in these classes are a major contributor to undergraduates leaving Stem degrees. We know people who are rote learners struggle with science, and if we can identify them early, we can change the curriculum and put in supplemental support, study co-author Regina Frye tells Chemistry World. Since we have shown that their concept-building approach does predict their effective performance, now we are looking at what types of interventions you may use that could help these students.

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Chemistry onstage makes Faith Hill and Tim McGraw a top tour – Toledo Blade

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LAS VEGAS The love story of Tim McGraw and Faith Hill started on a tour two decades ago and that sparkling chemistry onstage has made them one of the genres biggest headliners.

The country couple with movie star glamour have sold more than 63 million albums in the U.S. between their two careers, earned two Grammys for duets they sang together, and have three children. This year, they are releasing their first-ever duet album together and started their third installment of their highly successful Soul2Soul World Tour (it launched last week).

Faith Hill, left, and Tim McGraw appear at the 52nd annual Academy of Country Music Awards in Las Vegas.

Invision Enlarge

I havent been on a stage like this in 10 years and that is no lie, Hill said of the tour. I can tell you right now I am fired up.

During an Associated Press interview with the couple, Hill and McGraw were giddy with anticipation.

Shes ready to turn it loose, McGraw said.

Age is not an issue, added Hill, who together with her husband will be turning 50 during the tour that runs through October, including stops in Cleveland, Columbus, and Detroit.

The Mississippi-born Hill and the Louisiana-born McGraw fell in love when she opened for him on his 1996 Spontaneous Combustion tour and they married that year.

In 2000, the first Soul2Soul tour grossed $48.8 million, making it the best grossing country tour in North Americathat year, according to Pollstar. The Soul2Soul II tour was even more successful, grossing $88.8 million in 2006, and made it the 3rd highest grossing North American tour that year.

McGraw credited their success on the road to the fact that they are very different singers who push each other to expand their ranges onstage.

Faith, I would say, is more of an R&B, sort of gospel-inspired singer, McGraw said. And I think I am more a 70s rock, arena rock, Merle Haggard meets arena rock kind of singer. She brings me a little bit more to the R&B side, and I bring her more to the arena rock side, and I think it creates a sort of magic.

Their first duet together, Its Your Love, was on McGraws 1997 Everywhere album, which was followed by Just to Hear You Say That You Love Me, from Hills multiplatinum album Faith. Since then, they have had several popular duets, including their latest, Speak to A Girl, which jumped into the Top 10 of Billboards Hot country songs chart after they performed it on the ACM Awards.

But they say they dont always agree in music, or in marriage, but McGraw said commitment is key.

Look, there is no secret, Hill said. Either you like one another or you dont. You want to stay married or you dont. You work at it, or you dont. Simple as that. It is not always easy and there are moments that are rocky.

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Chemistry onstage makes Faith Hill and Tim McGraw a top tour - Toledo Blade

Blue Jays’ Jarrod Saltalamacchia: Developing chemistry with Marco Estrada – CBSSports.com

Saltalammachia received high praise from Saturday's batterymate, Marco Estrada, and the two have developed productive chemistry that could lead to more playing time for the catcher, Laura Armstrong of the Toronto Star reports.

Saltalamacchia, who signed with the Jays in the offseason, has started just two of the team's first 13 games while amassing a measly 10 at-bats. However, the door may be open to increased plate appearances after Estrada -- who struggled last time out -- pointed to the 31-year-old's influence as a key to the pitcher's seven scoreless innings. "It was the way Salty called the game. I was just trying to follow him, elevated a lot of fastballs and had them swinging at it," said the right-hander. As of now, Saltalamacchia is unworthy of a fantasy roster spot. But, if he settles in as Estrada's routine catcher, then the veteran could turn up as a nice value play in daily leagues on occasion.

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Arizona State coach talks team chemistry for regionals – Golf Channel

Arizona State coach talks team chemistry for regionals
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Arizona State coach talks team chemistry for regionals. Arizona State women's golf head coach Missy Farr-Kaye and her team are excited to be the No. 2 seed in the Lubbock Regional for 2017 NCAA Division I Women's Golf Regionals. PlaylistTrending.

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New Rider chemistry fellowship honors 3 former faculty members – News at Rider


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New Rider chemistry fellowship honors 3 former faculty members
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Rider University has announced the launch of a new endowed research fellowship for chemistry students in honor of three of Rider's most successful and passionate professors. The Endowed Chemistry Research Fellowship in Honor of Professors Burnham, ...

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Chemistry, and its impact on next year’s Syracuse basketball team … – Troy Nunes is an Absolute Magician

Have you ever been on a team with mostly new players trying to come together? Its tough, right?

Now remember a time where you were on a team that was built with players who were familiar with each others tendencythat team experienced more success, more often than not.

The first scenario sounds pretty familiar to what the Syracuse Orange showcased this season: a team full of individuals that werent used to each others talents. While this years team had a plethora of experience in age, the reality was that the impact players were mostly freshmen or transfer players.

Tyler Lydon was the glue that held things together, but the other four starters by years-end were in their first season of playing under coach Jim Boeheim. No matter how much talent is on the floor, playing together as a team is a whole new story.

The Orange struggled at times to get any motion going on the offensive end of the court, and that could be in large part to the players unfamiliarity with each other. We saw improvements throughout the year, but just imagine if these guys had the chemistry of the prior seasons team.

The 2015-2016 Syracuse Orange were built on chemistry. Michael Gbinije and Trevor Cooney were the backbone to the Syracuse offense, and their experience as graduate students surely helped. Their familiarity with each other helped the Orange work through stagnant times on offense.

Tyler Roberson and DaJuan Coleman, the core of the Orange defense, were upperclassmen as well. The two big-men knew the ins-and-outs to Boeheims 2-3 zone, unlike this years team with Taurean Thompson and Andrew White III teaming up with Tyler Lydon down low.

Then came the freshmen. Tyler Lydon and Malachi Richardson looked like freshmen to begin the season, but by the end of the year the two new guys were more than helping Syracuse make a run to the Final Four.

So, you may be asking where Im going with this. By no means am I comparing next years team to the most recent Final Four team, but maybe we can take a look at the similarities and focus on some positives for whats to come.

Next years team wont have much upperclassmen talent, but Boeheim will be looking for his sophomores in Tyus Battle and Taurean Thompson to act like they have that kind of experience.

Frank Howard will be running the show at point guard as the lessons he learned in his first two seasons will hopefully lead to it all coming together. Matthew Moyer is coming off his redshirt season, and if he puts the work in this off season he may be able to play the sidekick role Battle needs on the wing.

Paschal Chukwu is coming off of a lost season, but he along with the names mentioned above have experienced time on the court together. These five returning players arent the stars the 2015-2016 team had, but chemistry means everything, and this team will have the experience of playing with each otherwhether that be in games or practice.

Next years squad will also have impact freshmen in Oshae Brissett, Howard Washington, and Bourama Sidibe. These guys may not have the impact Richardson and Lydon had in their freshmen seasons, but if they find a way to contribute on both ends of the floor they will be earning more playing time as the season goes by.

There are still more recruits who may sign and transfer players who may find their way over to the Carrier Dome, so this roster of returners and newbies may expand. Dont expect this team to look like the 2015-2016 team, but having high chemistry doesnt a hurt a team looking for positives.

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Chemistry, and its impact on next year's Syracuse basketball team ... - Troy Nunes is an Absolute Magician

PHS chemistry teacher emerges as Yavapai County Outstanding First-Year Teacher award finalist – The Daily Courier

In his first year in the classroom, and as a junior varsity basketball coach, Prescott High School chemistry teacher Todd Harris Jr. landed more than a job.

Hes found a calling.

I really do love this job, said the Montana native who graduated from the University of Great Falls with his bachelors degree in secondary education in broad field science in May 2015 and did his student teaching at Prescott High his final spring semester. Im really looking forward to my next year and all that will have in store.

A basketball player from childhood, Harris pursued teaching because it seemed a profession that most closely aligned to his passion for coaching youth basketball. Match that with an affinity for science, in particular chemistry, his degree seemed to make perfect sense, he said.

What Harris could not know was how well-suited he would be for the teaching profession.

It has surprised me, Harris admits, noting his college and student teaching prepared him but until one is front and center every day in a classroom, the realities are something of a mystery.

At 22, Harris came to the high school as the youngest member of the faculty, only a few years older than his oldest students.

Yet Harris age has never been a factor in his classroom demeanor. He has commanded respect from day one, according to his students, fellow faculty and administrators.

He really relates to his students, and is always very approachable, said Cheyenne Church, a senior and the districts Governing Board student representative, who took chemistry with Harris when he was student teaching but regularly hears accolades from fellow students about his teaching skills. I actually think the fact he is just out of college

has been a selling point for him because he has that fresh, firsthand perspective of what its like to be a student. He really understands the struggles students are going through, and I think he uses that to determine course load and how he explains things. He looks at his explanations through the eyes of a student, not as one of a professor.

Hes the best first-year teacher Ive ever seen.

Such praise is the backbone of Harris becoming one of three finalist for Outstanding First-Year Teacher in the 23rd annual Yavapai County Teacher of the Year program sponsored by the Yavapai Education Foundation. The other two finalists are Lisa Fuller, a kindergarten teacher at Dr. Daniel Bright Elementary School in the Cottonwood-Oak Creek District, and Stephen Ross, a math teacher at Bradshaw Mountain High School in the Humboldt Unified School District. The finalists were narrowed from a field of 15 nominees.

In a nomination letter representing Prescott High School staff, Principal Stephanie Hillig described Harris as a teacher who brings a contagious energy into his classroom through innovative, creative and enthusiastic approaches to what can be complex scientific concepts.

Students are excited about going to science class every day, Hillig said.

From his beginnings as a student teacher, Hillig said it was clear that Harris had all the attributes the school was seeking in their science department, and has demonstrated exemplary qualities in his classes that include the advanced placement course.

One of the strengths in Mr. Harris instruction is that he finds ways to make chemistry relative to future classes and careers, Hillig said. Mr. Harris philosophy is that students need to learn by experimenting and discovering the answers on their own When one enters Mr. Harris classroom, it is as if you are entering a veteran teachers room as he clearly understands his curriculum and he is very confident with his delivery of instruction.

On the basketball court, Harris, too, imparts his passion for the game, as he said he believes this is a teaching sport that requires hard work, something Harris emphasizes is critical to any endeavor.

Whether he is teaching chemistry or coaching basketball, Hillig said he brings qualities of a veteran teacher with the enthusiasm and energy of a first-year teacher.

A humble, yet confident teacher and coach, Harris said he is beyond honored to be a finalist. The awards banquet is April 28.

Its cool to have such recognition in such a short time, Harris said. Its pretty exciting.

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PHS chemistry teacher emerges as Yavapai County Outstanding First-Year Teacher award finalist - The Daily Courier

Chocolate cake and chemistry repair US-China ties. But will North Korea spoil the party? – Washington Post

BEIJING It was a relationship sealed over the most beautiful piece of chocolate cake you have ever seen.

After a day spent getting to know each other at his estate in Palm Beach, Fla., President Trump broke some major news to his Chinese counterpart over dessert. Fifty-nine Tomahawk missiles were locked, loaded and then launched toward Syria.

[U.S. strikes Syrian military airfield in first direct assault on Bashar al-Assads government]

In Trumps retelling, Xi Jinping was silent for 10 seconds, ominously asked for the comments to be translated a second time and finally declared he was okay with the idea. And so the Citrus Summit, as it has been nicknamed, was to be a success.

In short order, China has gone from an enemy and a threat, a job stealer and economic predator, to becoming a friend and partner of the new U.S. administration. In interviews with theFox Business Network and theWall Street Journal, Trump said he and Xi shared great chemistry, had formed an outstanding relationship, and understood each other.

(Jenny Starrs/The Washington Post)

All of a sudden, U.S. policy toward China seems broadly similar to that pursued by his predecessor. Trump might be a very different personality than President Barack Obama, the Global Times newspaper commented Friday, but there are many signs he is returning to Obamas diplomatic strategy.

Yet how deep is this newfound friendship with China, and how sustainable is the relationship?

If Trump has flipped once, could he flip again?

The answer to that question could lie in North Korea.

Just before the summit, Trump told the Financial Times that the Chinese were the world champions of currency manipulation. A few days after it, he told the Wall Street Journalthat China does not manipulate its currency.

Acartoon in Chinas Global Times on Friday mocked Trump as the Shifter-in-Chief, showing him at the wheel of a bus careening all over the road, but the overall mood is upbeat here at what state media are calling the big flip.

[A moderate catches Trumps ear]

The immediate effect of the two-day summit has been to bring an influx of tremendous dynamism into the complicated U.S.-China relationship, wrote thePeoples Daily, the Communist Party mouthpiece. This transition is a masterpiece of erudite political wisdom.

The erudite wisdom, one assumes, is supposed to be coming from the mouth of Chinas president, into the ear of the American one. Indeed, the Peoples Daily naturally chose aphotograph of Trump listening attentively to Xi speaking to adorn its post-summit front page.

Of course, it chosesimilar images in 2013, when Xi met Obama in Californias Sunnylands retreat and was again portrayed as the man delivering pearls of wisdom to his enraptured counterpart.

But this time there is real reason to believe that some of Xis arguments struck home, and not just in getting Trump to finally realize he was years out of date when it came to Chinas currency policy.

Just as no one could have imagined how complicated health care was, until you actually took the time to learn about it, Trump is fast learning the complications of tackling North Korea, thanks to some schooling from the Chinese president.

For months, the U.S. president had been firing off confident 140-character promises that he would solve the problem of Pyongyangs nuclear program, apparently believing that China could bring its neighbor to heel if it only wanted to. But Xi took the trouble to explain something about the history of China and Korea.

And after listening for 10 minutes I realized that its not so easy, Trump told the Journal. You know I felt pretty strongly that they have a tremendous power over North Korea. ... But its not what you would think.

This is not the first time Trump has changed tack. He questioned the one-China policy earlier this year before deciding to honor it, and has quietly dropped campaign threats to impose tariffs of up to 45 percent on Chinese goods.

Thats partly because he is learning as he goes along, sometimes slowly, sometimes painfully, always in full public view, experts say.

It is partly a function of the rise of the globalists within his administration, includingJared Kushner andGary Cohn, and the declining influence of the nationalists, such asStephen K. Bannon andPeter Navarro. But it is also a dawning of the realization that Trump needs a constructive relationship if he is to achieve his other foreign policy goals.

Ever since diplomatic ties with China were normalized nearly four decades ago, candidates have generally campaigned on being tough on China, before reverting to a more constructive approach while in office.

But if history is repeating itself, Trump represents an extreme case of the phenomenon.

For Bill Bishop, the publisher of theSinocism newsletter, there is a danger in making so many threats only to walk them back, and a missed opportunity to reexamine a policy approach that has brought more benefits to China than the United States.

The currency flip-flop made sense from an economic perspective, but one has to wonder how tough Beijing thinks Trump really is, and if Xi, a fan of Mao Zedong, sees Trump as yet another American paper tiger, he said.

It is too bad. America needs a new approach to dealing with the China challenge, one that is well thought out and strategically coherent. So far that does not appear to be happening, and that is good for Xi and the PRC [Peoples Republic of China] but not so good for the U.S.

Others take a different view.

President Richard Nixon is reported to have deliberately cultivated the Madman Theory, giving the impression he was irrational and volatile, and might even use nuclear weapons, in an attempt to scare the North Vietnamese and the Soviet Union. The credible threat of military action by the George W. Bush administration may have helped bring North Korea back to the negotiating table in 2006.

In a similar vein, Trumps decision to bomb Syria while hosting Xi was a shrewd move, some argue, helping to persuade Beijing to turn up the heat on its ally. In February, China announced it wascutting off coal imports from North Korea, severing an important economic lifeline for the regime, and has since reportedly turned back two coal shipments.

China does move on North Korea if they are sufficiently scared of the U.S., said Daniel Blumenthal of the American Enterprise Institute. They may pressure Kim if we keep the pressure on China.

Orville Schell, head of the center on U.S.-China relations at New York's Asia Society, said real world realities are beginning to bring Trumps policy closer to that of Obama, but the difference is Trumps utterly unpredictable nature, and his capacity to reverse course in a heartbeat.

Schell said this had put China somewhat off balance, uncertain if Trump might impose secondary sanctions or even launch a military strike on North Korea.

This kind of brinkmanship can be dangerous in diplomacy, but it could also get Beijing's attention and chasten Xi to make a deal before something untoward happens, Schell said.

Paul Gewirtz, director of the Paul Tsai China Center at Yale Law School, said China may impose tougher sanctions against North Korea, but not because Trump tells it to.

Those are likely to come from an ongoing assessment of Chinas interests and rising Chinese public opinion against North Korea, he said.

In the end, though, China and the United States have significantly different approaches to the issue of North Korea, and this fact alone remains a major challenge to the new rapport between Xi and Trump.

The evolution toward a more constructive relationship is certainly welcome, said Paul Haenle, director of the Carnegie-Tsinghua Center. But I think the big question is whether or not this can be sustained once the Chinese begin to underperform on trade or North Korea as times goes on. Will Trump be willin
g to confront his new friend Xi Jinping in order to defend U.S. interests?

Jin Xin, Luna Lin and Congcong Zhang contributed to this report.

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Chinas Xi calls Trump, urges peaceful approach to North Korea

Despite Trumps rage against China, American public opinion is warming to the Asian giant

Dont let Beijing push us around, warns frustrated former ambassador to China

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Chocolate cake and chemistry repair US-China ties. But will North Korea spoil the party? - Washington Post

Can chemistry issues with Ashton Hagans be resolved? – Vaught’s Views

Ashton Hagans (Vicky Graff Photo)

By LARRY VAUGHT

Does Kentucky have chemistry issues?

It sure looks like it could with the recent decline in point guard Ashton Hagans play combined with whatever caused him to tell coach John Calipari he was not going back in the game against Tennessee Tuesday before he did and played very poorly as UK was blowing a 17-point lead and losing.

Hagans and teammate Nick Richards exchanged words on the court. Maybe it was Richards complaining about not getting the ball. Maybe it was Hagans urging Richards to rebound. Maybe it was Richards telling Hagans to get his head in the game, especially after one turnover where he jogged back on defense that resulted in a 3-point play for Tennessee.

Neither one played particularly well, so probably telling each other, Youre not playing well, and neither are you, neither are you, neither are you.,' UK coach John Calipari said after the game in an obvious attempt to downplay the situation that played out on national title.

What about the bad looking body language on the court often during the 17-point Tennessee comback?

We have been on a heck of a run. This team has done a lot of good stuff, and the one thing we worry about is if the game is going to be physical, like, Nicks getting, you know, then we have got to learn to play in these kinds of games, Calipari said.

Notice he did not answer the question.

Calipari noted once out of a timeout he called a play to get a shot at the basket and instead another player took a jump shot.

Come on.We got manhandled, I got manhandled, Calipari said.

Im not sure if it was manhandled as much as just outhustled. Kentucky quit playing. Maybe its not fair to put most of the blame on Hagans but hes been on a bigger downward trend that Immanuel Quickley has been on an upward trend.

Remember this was supposed to be Hagans team. He was SEC Defensive Player of the Year as a freshman and we heard how he was going to be an improved offensive player. Ive never questioned his competitiveness or toughness. Hes played through injuries and he doesnt back down from anyone.

But he also pictures himself as a NBA player next year, something I cant quite get with his offensive deficiencies. Could he be trying to impress NBA scouts too much maybe without even realizing it?

One SEC coach told me the best way to counter Hagans is to rattle him mentally. Question his ability to score. Dare him to take open shots. Back off him and leave him open. Challenge him to try and drive inside to score. The theory is that Hagans wont have the patience to avoid being driven to show opponents he can answer the insults.

If he controls the pace, looks for teammates and doesnt try to do too much, then Kentucky is really, really good, the coach said. But if you can get him off his game, make him rush or try to do too much, then he sometimes makes mistakes.

Calipari has shown time after time he believes Kentucky is better with Hagans on the court. Cant see him changing his thinking now. So heres hoping whatever might be going on with Hagans and the Cats gets corrected and no reason to think it cant or the Cats can forget having an enjoyable Marfch.

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Can chemistry issues with Ashton Hagans be resolved? - Vaught's Views

PREVIEW: Department of Chemistry to host Arudengo Chemistry lecture – The University of Alabama Crimson White

By Isabella Garrison | 04/13/2017 9:46pm Jake Stevens / Alabama Crimson White

A reception will follow the annualArudengo Lecturein the Shelby Hall rotunda.

This weekend, the annual tradition of the Arudengo Lecture on element chemistry or physical organic chemistry continues with a speech from a renowned specialist from the University of California, Berkeley. The lecture will discuss the role that certain oxidized metal species will play in the future of producing solar fuels.

WHO: The event is hosted by the University's Department of Chemistry and it is free and open to the public.

WHAT: Professor T. Don Tilley from the University of California, Berkeley will give the annual Arduengo Lecture. Professor Tilleys lecture is entitled, The Role of Highly Oxidized Metal Species in Water Splitting and Solar Fuels Production.

A reception will follow the lecture in the Shelby Hall rotunda.

WHEN: Friday, April 14, from 3:30-4:30 p.m.

WHERE: 1093 Shelby Hall

WHY: According to the University's website, the Arduengo Lectureship was established to honor the contributions of Professor Anthony J. Arduengo III. The annual lecture is given by a world-renowned researcher in the area of main group element chemistry or physical organic chemistry. Lecturers are chosen by a faculty committee in recognition of their contributions to their field. Professor Tilley will give both a technical and a general audience talk.

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PREVIEW: Department of Chemistry to host Arudengo Chemistry lecture - The University of Alabama Crimson White

Deaf student trail-blazing her way to a chemistry degree – Colorado State University News (press release)

Evie Bangs was 5 years old when she started to lose her hearing. At age 8, her hearing plummeted, and she could no longer understand her teachers.

Now shes about to graduate from Colorado State University. And shes gotten here not by dwelling on what she has lost, but focusing on what she could gain and soon, that will include a degree in chemistry from the College of Natural Sciences.

Bangs may be CSUs first deaf chemistry major at least in anyones institutional memory. Its taken Bangs an extra year to finish her degree, in part because of the uniquely time-consuming way she must absorb challenging course material, with the help of sign language interpreters.

When Im in my classes, its kind of overwhelming, said the Estes Park native. I realized that in order to do well grade-wise, I needed to take fewer credits.

Bangs has also spent that extra time working toward an American Chemical Society-certified degree, which requires additional training and lab work. Bangs aspires to attend graduate school, and become a professional chemist.

For every class, as well as for group projects, Bangs is accompanied by two American Sign Language interpreters and one class transcriber from CSUs Resources for Disabled Students (RDS). Her teachers joke that Bangs has an entourage.

The two interpreters are necessary due to the complexity of the material; sometimes, while one is working with Bangs to quickly make up signs for words like stoichiometry or adiabatic process, the other is continuing to listen to the instructor, so that Bangs misses as little as possible. Halfway through class, they switch roles. Its called teaming, says RDS interpreter Dede Kliewer, and through the years of working with Bangs, everyone including the interpreters has learned a lot about chemistry.

Like many deaf people, Bangs can read lips, but even the best lip-readers catch 60 percent or less of whats being said. She can get by one-on-one, but in groups or lectures, sign language and notes transcribed after the fact have been Bangs primary modes of learning.

RDS, part of the Division of Student Affairs, has eight sign language interpreters and 26 class transcribers, says Kliewer, who interpreted for her when Bangs was a freshman. The office also employs about 30 student notetakers. In Kliewers 24 years at CSU, she cant recall another chemistry major, although theyve had biology majors, and a chemical engineering graduate student.

It was a high school teacher who first encouraged Bangs to study chemistry in college. As a CSU freshman, Bangs enjoyed Professor Alan Van Ordens General Chemistry for Majors course. I remember he said on the first day, Welcome to chemistry the study of stuff! And I thought, I dont care how hard chemistry is going to be. Im sticking to it!'

Besides Van Orden, Professor Nancy Levinger was a memorable teacher for Bangs. She helped me out a lot, Bangs said. Levingers door was always open to Bangs for extra help. She took the time to write detailed lecture material on the board. And when Bangs interpreters were switching roles mid-class, Levinger would pause to let them catch up. It wasnt harming the other students, but in a way, Dr. Levinger was taking care of me, Bangs said.

Bangs holds a denuder train, an instrument for active sampling of ambient ammonia, nitric acid and PM (particulate matter) 2.5.

Professor Delphine Farmers class on environmental chemistry sparked in Bangs an interest in atmospheric research. In her junior year, Bangs became an undergraduate research assistant in the lab of Professor Jeff Collett, chair of the Department of Atmospheric Science. Shes involved in two projects now, supervised by research scientist Katie Benedict, in passive and active sampling of atmospheric ammonia all over northeastern Colorado. Recently, she co-authored a paper on the role of dew as a nighttime ammonia reservoir her first academic publication.

Bangs says her family, teachers, classmates and friends have played active roles in her journey. But perhaps most of all, the RDS interpreters have helped her succeed as a student. They were a bright spot on the bad days, she says. Sometimes I was not looking forward to class, but I looked forward to seeing my interpreters.

Bangs also learned to keep lines of communication open with her professors introducing herself at the start of the semester, and taking advantage of office hours.

If their door was cracked, I was knocking on it, Bangs says. She added, Everywhere I go, here at CSU, people have filled in the gaps for me. They made it so that I could be successful.

Between working in Colletts lab and keeping up with classes, Bangs found time to volunteer in some of Kliewers American Sign Language courses. Last semester, she visited a local elementary school, where she met a fifth-grade boy whose little brother had just been born deaf. The interaction moved her to be more open about her experiences.

While being deaf sometimes requires special assistance, it is only part of a bigger story, she says.

Im not remarkable, Bangs insists. I am just like everyone else. My story is just a little different; being deaf is a tribulation that I had to get over. My cards were dealt, and others have their own challenges that they need to get over, too. Deafness, anxiety, anything at all everyone has a story.

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Deaf student trail-blazing her way to a chemistry degree - Colorado State University News (press release)

Stretchy ionic polymers pave the way for ion-based tech – Chemistry World

Researchers in the US have developed soft and stretchable devices that operate using ionotronic technology without the need for a liquid electrolyte. The work boosts the prospect of ionotronic devices being used in soft robotics, humancomputer interfaces, wearable sensors and energy harvesting.

In ionotronic technology, ions are the charge carriers rather than electrons. Using soft ion-conducting materials such as hydrogels and polymers offers the prospect of inherently flexible circuits and since most biological signalling also uses ions, it could be a route to creating interfaces between humans and machines. Previous studies into ionotronic devices have used hydrogels with salt water solutions to carry charges. But liquid electrolytes are prone to leak or evaporate when the devices are stretched or deformed.

Now, Ryan Hayward and his team at the University of Massachusetts have developed ionotronic devices using stretchy ionelastomers that dont require liquid electrolytes. Our material relies on soft networks of charged polymers where the counterions are the only mobile species. In addition, our devices operate without requiring any electrochemical reactions, which can alleviate issues of long-term device instability, Hayward explains.

The team made two rubber band-like ionoelastomers: a polyanion and a polycation. In the polyanion, negatively charged sulfate groups are fixed to the elastomer chain while positive imidazole counterions are free to move. The reverse applies to the polycation the negative ions are fixed but the positive ions can move.

This means each material conducts only positive or negative charge, similar to the way p- and n-type semiconductors transport holes and electrons respectively. The materials can therefore be combined to create ionic analogues of semiconductor electronic components. For example, a junction between layers of opposite polarity acts like a diode, allowing current to pass in one direction but not the other.

The team also created a transistor by sandwiching a polycation layer between two polyanion layers. A third device was able to harvest mechanical energy that was produced when stretching and compressing it.

This represents an important next step for iontronics, says Daniel Frisbie who investigates semiconducting devices at the University of Minnesota, US. Combining ionic conductivity with elastomeric properties in a single material is the creative aspect of this work that opens up new possibilities, for example in soft robotics or humanmachine interfacing.

Hayward suggests that the range of ionic species that could be used as charge carriers offers further scope for invention. Attaching other functionalities that influence optical characteristics, surface energy, or even bioactivity would allow the properties of the material to be electronically switched, he explains.

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Stretchy ionic polymers pave the way for ion-based tech - Chemistry World

Chemist Andy McNally honored with 2020 Sloan Research Fellowship – Source

Andy McNally, assistant professor of chemistry

Andy McNally, an assistant professor in the Colorado State University Department of Chemistry, has received a 2020 Sloan Research Fellowship, the Alfred P. Sloan Foundation has announced.

McNally is an experimental synthetic chemist whose lab invents new chemical reactions for faster and more efficient synthesis of therapeutic compounds, as well as new drug candidates. He is among 126 early-career researchers to receive the honor, chosen from nearly 1,000 nominees.

Awarded annually since 1995, Sloan fellowships honor scholars in the U.S. and Canada whose creativity, leadership and independent research achievements make them some of the most promising researchers working today, according to the foundation.

At CSU, McNally leads a laboratory focused on the unique chemistry of phosphorus compounds to functionalize pyridine and diazine heterocycles, which are central to how many pharmaceutical agents function. However, it is challenging to make the types of derivatives required in drug-discovery campaigns using existing chemical methods.

McNallys group has developed a suite of new reactions that are being used by medicinal chemistry groups across the country to discover new pharmaceuticals. His groups flagship project, published in Science in 2018, is a new method to link two pyridine heterocycles together using phosphorus intermediates instead of late-transition metals such as palladium.

With the funds from the Sloan fellowship, his group plans to extend these methods for protein bioconjugation a way of forming chemical bonds to specific amino acid residues in biomolecules as a means of studying and treating diseases.

McNally, who joined the CSU faculty in 2014, was previously a Marie Curie International Fellow at Princeton University, where he worked on high-throughput screening methods for new chemical reactions. He has an M.A. and M.Sci. in natural sciences, and a Ph.D. in chemistry, all from University of Cambridge.

According to the Sloan Foundation, past Sloan Research Fellows include many towering figures in the history of science, including physicists Richard Feynman and Murray Gell-Mann, and game theorist John Nash. Fifty fellows have received a Nobel Prize in their respective field, 17 have won the Fields Medal in mathematics, 69 have received the National Medal of Science, and 19 have won the John Bates Clark Medal in economics, including every winner since 2007.

Fellows for 2020 were drawn from more than 60 institutions across the U.S. and Canada. Fellowships are open to scholars in eight scientific and technical fields chemistry, computer science, economics, mathematics, computational and evolutionary molecular biology, neuroscience, ocean sciences, and physics. Sloan Research Fellows are nominated by fellow scientists, and winners are selected by an independent panel of senior scholars. Nearly 1,000 researchers are nominated each year for 126 fellowships.

Winners receive a two-year, $75,000 award, which can be spent to advance the fellows research.

At CSU, 16 researchers have received Sloan Fellowships in the last five decades, all within the College of Natural Sciences. Recent winners were Jamie Neilson in 2017 and Amber Krummel in 2015, also both faculty in the Department of Chemistry.

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Chemist Andy McNally honored with 2020 Sloan Research Fellowship - Source